A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
It is this lack of combining power, of course, that explains the
non-discovery of these elements during all these years, for the
usual way of testing an element is to bring it in contact with other
substances under conditions that permit its atoms to combine with
other atoms to the formation of new substances. But in the case of new
elements such experiments as this have not proved possible under any
conditions as yet attained, and reliance must be had upon other physical
tests--such as variation of the bulk of the gas under pressure, and
under varying temperatures, and a study of the critical temperatures
and pressures under which each gas becomes a liquid. The chief reliance,
however, is the spectroscope--the instrument which revealed the presence
of helium in the sun and the stars more than a quarter of a century
before Professor Ramsay ferreted it out as a terrestrial element.
Each whiff of colorless gas in its test-tube interferes with the light
passing through it in such a way that when viewed through a prism it
gives a spectrum of altogether unique lines, which stamp it as krypton,
neon, or zenon as definitely as certain familiar and more tangible
properties stamp the liquid which imprisons it as mercury.
QUERIES SUGGESTED BY THE NEW GASES
Suppose that a few years ago you had asked some chemist, "What are the
constituents of the atmosphere?" He would have responded, with entire
confidence, "Oxygen and nitrogen chiefly, with a certain amount of
water-vapor and of carbonic-acid gas and a trace of ammonia." If
questioned as to the chief properties of these constituents, he would
have replied, with equal facility, that these are among the most
important elements; that oxygen might almost be said to be the
life-giving principle, inasmuch as no air-breathing creature could get
along without it for many moments together; and that nitrogen is equally
important to the organism, though in a different way, inasmuch as it is
not taken up through the lungs. As to the water-vapor, that, of course,
is a compound of oxygen and hydrogen, and no one need be told of its
importance, as every one knows that water makes up the chief bulk of
protoplasm; carbonic-acid gas is also a compound of oxygen, the other
element this time being carbon, and it plays a quite different rôle in
the economy of the living organism, inasmuch as it is produced by the
breaking down of tissues, and must be constantly exhaled from the lungs
to prevent the poisoning of the organism by its accumulation; while
ammonia, which exists only in infinitesimal quantities in the air, is a
compound of nitrogen and hydrogen, introducing, therefore, no new
element.
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