A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.Humphrey, S. D. (Samuel Dwight)
Science
A Practical Manual of the Collodion Process, Giving in Detail a Method For Producing Positive and Negative Pictures on Glass and Paper.
Humphrey, S. D. (Samuel Dwight)
Ambrotype; Photography
This is a gaseous compound of hydrogen and iodine, corresponding in
composition to the hydrochloric acid. It cannot, however, from its
instability, be obtained in the same manner, since, on distilling
an iodide with sulphuric acid, the hydriodic acid first formed is
subsequently decomposed into iodine and hydrogen. An aqueous solution of
hydriodic acid is easily prepared by adding iodine to water containing
sulphuretted hydrogen gas; a decomposition takes place, and sulphur is set
free; thus: HS + I = HI + S.
_Properties._--Hydriodic acid is very soluble in water, yielding a
strongly acid liquid. The solution, colorless at first, soon becomes brown
from decomposition, and liberation of free iodine. It may be restored to
its original condition by adding solution of sulphuretted hydrogen.
Hydrosulphuric Acid.
Symbol, HS. Atomic weighty 17.
This substance, also known as sulphuretted hydrogen, is a gaseous compound
of sulphur and hydrogen, analogous in composition to hydrochloric and
hydriodic acids. It is usually prepared by the action of dilute sulphuric
acid upon sulphuret of iron, the decomposition being similar to that
involved in the preparation of the hydrogen acids generally:--
FeS + HO SO{3} = FeO SO{3} + HS.
_Properties._--Cold water absorbs three times its bulk of hydrosulphuric
acid, and acquires the peculiar putrid odor and poisonous qualities of the
gas. The solution is faintly acid to test-paper, and becomes opalescent on
keeping, from gradual separation of sulphur. It is decomposed by nitric
acid, and also by chlorine and iodine. It precipitates silver from its
solutions, in the form of black sulphuret of silver; also copper, mercury,
lead, etc.; but iron and other metals of that class are not affected, if
the liquid contains free acid. Hydrosulphuric acid is constantly employed
in the chemical laboratory for these and other purposes.
Hydrosulphate of Ammonia.
Symbol, NH{4}S HS. Atomic weight, 51.
The liquid known by this name, and formed by passing sulphuretted hydrogen
gas into ammonia, is a double sulphuret of hydrogen and ammonium. In the
preparation, the passage of the gas is to be continued until the solution
gives no precipitate with sulphate of magnesia and smells strongly of
hydrosulphuric acid.
Properties,--Colorless at first, but afterwards changes to yellow, from
liberation and subsequent solution of sulphur. Becomes milky on the
addition of any acid. Precipitates, in the form of sulphuret, all the
metals which are affected by sulphuretted hydrogen; and, in addition,
those of the class to which iron, zinc, and manganese, belong.
Hydrosulphate of ammonia is employed in photography to darken the negative
image, and also in the preparation of iodide of ammonium; the separation
of silver from hyposulphite solutions, etc.
Hyposulphite of Soda.
Symbol, NaO S{2}H{2} + 5 HO. Atomic weight, 125.
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