The alkali employed may be either caustic lime, caustic {83} soda, sodium carbonate, or a mixture of the latter and lime, which is of course equivalent to using caustic soda. The proportion of alkali depends upon so many considerations that it is quite impossible to give exact information on this point. In the case of caustic soda, a quantity equal to from 5–10 per cent. on the rags may be taken to be a fair average. If lime be used it should be slaked with water, made into a thin milk and carefully filtered through fine wire cloth to keep back the particles of sand, coal, &c., which lime is always liable to contain. From 5–10 per cent. may be used. The amount of lime actually dissolved in the water is relatively small (1·3 grms. per litre); the portion in solution however, rapidly combines with the grease, dirt, and colouring matter of the rags and forms with them insoluble compounds, a fresh portion of lime being at the same time dissolved. This formation of insoluble compounds constitutes an important objection to the use of lime, as they are liable {84} to remain to some extent fixed in the rags and are with great difficulty removed by washing. For this reason, therefore, the more soluble alkali is to be preferred. Moreover, the lime sometimes tends to exert a hardening effect upon the cellulose. Notwithstanding these objections, lime is used by some paper-makers in preference to soda. In making choice of the chemical for boiling, much depends on the quality of the rags and the nature of the paper for which they are intended, so that no definite rules can be given. The time of boiling varies from 2 to 6 hours, according to the quality of rags, the chemical employed, and the pressure. The use of very high pressures should be avoided as far as possible, as there is a danger, owing to the correspondingly high temperature, of _fixing_ the dirt and colouring matters instead of dissolving them. The quantity of water should be kept as low as may be, in order to have as strong a solution of alkali as possible; this effects a saving both in the time of boiling, and in the alkali. This is of great importance where it is necessary to evaporate the whole of the waste liquors. It should also be remembered that a certain amount of water is always formed by condensation in all boilers in which live steam is used. On the other hand, if too little water be added, the rags are liable to become “burned” and the fibre therefore weakened. During the operation the boiler should be made to revolve slowly, in order to produce thorough circulation of the liquor.