American Horological Journal, Vol. I, No. 1, July 1869: Devoted to Pratical Horology
Science
American Horological Journal, Vol. I, No. 1, July 1869: Devoted to Pratical Horology
Clocks and watches -- Periodicals
Every chemist is familiar with the reduction of chloride of silver
in the form of powder by means of metallic zinc in the presence of a
little free acid. It is not easy to bring two such substances as the
silver salt and the metal into close contact, and after the work is
accomplished the removal of the excess of zinc has its difficulties.
Dr. Grager suggests a modification of the old method that ought to
be more generally made known. The chloride of silver is dissolved
in ammonia and poured into a well-stopped bottle, and into this is
introduced an excess of metallic zinc, in not too small fragments, so
that any reduced metal adhering to it may be readily washed off.
The decomposition begins immediately, and is rapidly accomplished,
especially if the contents of the flask be well shaken up. Three hours
will suffice to reduce one-quarter of a pound of chloride of silver.
It is easy to ascertain when the reduction is ended, by testing a
portion of the ammoniacal solution with hydrochloric acid. As soon as
no cloudiness or curdy precipitate is formed, the work may be regarded
as completed.
A slight excess of ammonia is said to be favorable. The reduced silver
must be washed with water until all odor of ammonia has disappeared.
The pieces of zinc are removed by pouring the contents of the flask
through a funnel, the opening of which is too narrow for the passage
of the zinc fragments, while the reduced silver can be easily washed
through. The finely divided silver can be digested in hydrochloric
acid to restore it to a pure white color, and it is then ready for
solution or fusion, and will be found to be perfectly pure. In dealing
with large quantities it would be economical to recover a portion of
the ammonia by distillation. In the same way an ammoniacal solution
of nitrate of silver can also be reduced by zinc, and the silver
obtained pure, even when the original solution of the nitrate contains
copper--provided a small quantity of silver be kept in the bath.
It is better where copper is present not to take all of the zinc that
may be requisite for the reduction of the silver. It will prove a
great convenience to be spared the necessity of converting the silver
into the chloride, as it is no easy task to wash out this salt on
filters--and it will be found to be applicable to alloys which do not
contain more than 25 per cent. of silver.--_From Prof. Joy in the
Journal of Applied Chemistry._
Transcriber’s Notes
Obvious errors in punctuation have been fixed.
Page 7: “Mechanique Celeste” changed to “Méchanique Céleste”
Page 12: “ou rexperience” changed to “our experience”
Page 18: “head-quarters far astronomical observations” changed to
“head-quarters for astronomical observations”
Page 22: “it accomodates” changed to “it accommodates”
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