ua
x = ----(1 - cos pt), if x = 0 when t = 0.
pd
Thus the greatest distance the ion can get from the plate is equal to
2au/pd, and if the distance between the plates is gradually reduced to
this value, the plate AB will begin to lose a negative charge; hence
when this happens
d = 2au/pd, or u = pd²/2a,
an equation by means of which we can find u.
In this form the method is not applicable when ions of both signs are
present. Franck and Pohl (_Verh. deutsch. physik. Gesell._ 1907, 9, p.
69) have by a slight modification removed this restriction. The
modification consists in confining the ionization to a layer of gas
below the gauze EF. If the velocity of the positive ions is to be
determined, these ions are forced through the gauze by applying to the
ionized gas a small constant electric force acting upwards; if
negative ions are required, the constant force is reversed. After
passing through the gauze the ions are acted upon by alternating
forces as in Rutherford's method.
Langevin (_Ann. chim. phys._, 1903, 28, p. 289) devised a method of
measuring the velocity of the ions which has been extensively used; it
has the advantage of not requiring the rate of ionization to remain
uniform. The general idea is as follows. Suppose that we expose the
gas between two parallel plates A, B to Röntgen rays or some other
ionizing agent, then stop the rays and apply a uniform electric field
to the region between the plates. If the force on the positive ion is
from A to B, the plate B will receive a positive charge of
electricity. After the electric force has acted for a time T reverse
it. B will now begin to receive negative electricity and will go on
doing so until the supply of negative ions is exhausted. Let us
consider how the quantity of positive electricity received by B will
vary with T. To fix our ideas, suppose the positive ions move more
slowly than the negative; let T2 and T1 be respectively the times
taken by the positive and negative ions to move under the electric
field through a distance equal to AB, the distance between the planes.
Then if T is greater than T2 all the ions will have been driven from
between the plates before the field is reversed, and therefore the
positive charge received by B will not depend upon T. Next let T be
less than T2 but greater than T1; then at the time when the field is
reversed all the negative ions will have been driven from between the
plates, so that the positive charge received by B will not be
neutralized by the arrival of fresh ions coming to it after the
reversal of the field. The number of positive ions driven against the
plate B will be proportional to T. Thus if we measure the value of the
positive charge on B for a series of values of T, each value being
less than the preceding, we shall find that until T reaches a certain
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