Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendixBattershall, Jesse P. (Jesse Park)
Science
Food Adulteration and Its Detection: With photomicrographic plates and a bibliographical appendix
Battershall, Jesse P. (Jesse Park)
Food adulteration and inspection; Food adulteration and inspection -- United States
In the gravimetric determination of the fat (butter), 10 grammes of the
milk are put into a tared platinum dish, containing a weighed amount of
dry sand. The milk is evaporated as previously directed, the mixture
being constantly stirred with a small platinum spatula. The residue
is repeatedly treated with warm ether or petroleum naphtha of 70° B.,
and the solutions poured upon a small filter. The several filtrates are
collected in a tared beaker, and cautiously evaporated, until constant
weight is obtained. This will give the amount of _fat_. The undissolved
residue remaining in the platinum capsule, or the difference between
the quantity of fat and that of the total milk-solids, affords the
proportion of _milk solids not fat_ contained, which, in unadulterated
milk, should amount to 9 per cent. It has been determined by
experiment, that every percentage of milk-solids not fat, increases
the specific gravity of milk 0·00375, whereas each percentage of fat
decreases the gravity 0·0010, and the proportion of solids not fat can
be calculated from the data afforded by the lactometer and Feser’s
lactoscope by means of the formula:--
(S - A) / 0·00375,
where S is the specific gravity of the milk, as shown by the
lactometer, and A is the remainder obtained upon multiplying the
percentage of fat indicated by the lactoscope by 0·001 and subtracting
the residue from 1·0000.
The residue remaining after the extraction of the fat is treated with
warm water containing a few drops of acetic acid, or with dilute (80
per cent.) alcohol, in order to remove the sugar. The residue is
dried until it ceases to decrease in weight, and is then weighed. The
difference between the original weight of the sand and the weight of
the sand and residue combined represents approximately the amount of
_caseine_ (albuminoids) present. As this contains a certain proportion
of ash it is to be subsequently ignited, and the ash obtained deducted
from the first weight. The alcoholic sugar solution is evaporated to
dryness and weighed. The residue is then incinerated and the weight
of ash is subtracted. The difference is the amount of _milk sugar_
contained. The sugar may likewise be determined by means of Fehling’s
solution (see pp. 37, 111). About 50 c.c. of the milk is warmed with
a small quantity of acetic acid to precipitate the caseine, which is
removed by filtration, and the filtrate diluted to 500 c.c.; the test
is then applied. 10 c.c. of the copper solution represents 0·067 gramme
of milk sugar.
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