The chloride of gold and sodium is prepared by dissolving common salt in
a solution of chloride of gold and then evaporating the solution. Sodium
chloro-aurate is also another name for this salt. Chloride of sodium is
common salt, and the chemical formula is NaCl, meaning that it is
composed of one part natrium (the Latin name for sodium) and one part
chlorine. The chemical formula for chloride of gold and sodium is NaCl,
AuCl_{3}+2H_{2}O, meaning that it is composed of one molecule of
chloride of sodium, one molecule of chloride of gold, to which are added
(+) two molecules of water. The chemical formula is also written in this
way: NaAuCl_{4}+2H_{2}O. When chloride of gold and sodium is used for
toning, a larger quantity by weight must be used than when the pure
chloride of gold is used.
A stock solution may be prepared by adding 15 grains of chloride of gold
and sodium to 7-1/2 oz. of water. (By a "stock solution" is meant a
solution that keeps for a long time, and may therefore be prepared in a
large quantity.)
The toning-bath is made by taking 3-1/2 oz. of water and pouring in the
gold solution till the mixture will turn blue litmus-paper red. (About
half an ounce will be sufficient.) To this mixture add bicarbonate of
soda until it turns the red litmus back to blue. This bath should be
prepared about half an hour before it is needed for toning. A saturated
solution (see first paper on simple chemistry) should be made of
bicarbonate of soda, and kept in stock.
Bicarbonate of soda is a fine white powder, soluble in ten parts of
water. It is used for neutralizing the excess of acid in gold
toning-baths. Natural deposits of bicarbonate of soda are found in
Africa, where it is called "trona," and in South America, where it is
called "urao." Its chemical formula is HNaCO_{3}.
Names of chemical elements mentioned and their atomic weight:
Atomic
Chemical Element. Symbol. Weight.
Carbon C 12
Chlorine Cl 35.5
Gold (Latin name Aurum) Au 196
Hydrogen (standard weight) H 11
Oxygen O 12
Sodium (Latin name Natrium) Na 23
Hydrogen is the lightest substance known, and an atom of hydrogen is
used as the standard weight by which all other atoms of the chemical
elements are weighed.
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