Alexander Just and Franz Hanaman in 1902 were laboratory assistants
to the Professor of Chemistry in the Technical High School in Vienna.
Just was spending his spare time in another laboratory in Vienna,
attempting to develop a boron incandescent lamp. In August of that year
he engaged Hanaman to aid him in his work. They conceived the idea of
making a lamp with a filament of tungsten and for two years worked on
both lamps. The boron lamp turned out to be a failure. Their means
were limited; Hanaman’s total income was $44 per month and Just’s was
slightly more than this. In 1903 they took out a German patent on a
tungsten filament, but the process they described was a failure because
it produced a filament containing both carbon and tungsten. The carbon
readily evaporated and quickly blackened the bulb when they attempted
to operate the filament at an efficiency higher than that possible with
the ordinary carbon filament. Finally in the latter part of the next
year (1904) they were able to get rid of the carbon and produced a pure
tungsten filament.
Tungsten had been known to chemists for many years by its compounds,
its oxides and its alloys with steel, but the properties of the pure
metal were practically unknown. It is an extremely hard and brittle
metal and it was impossible at that time to draw it into a wire. Just
and Hanaman’s process of making a pure tungsten filament consisted of
taking tungsten oxide in the form of an extremely fine powder, reducing
this to pure tungsten powder by heating it while hydrogen gas passed
over it. The gas combined with the oxygen of the oxide, forming water
vapor which was carried off, leaving the tungsten behind.
The tungsten powder was mixed with an organic binding material, and
the paste was forced by very high pressure through a hole drilled in
a diamond. This diamond die was necessary because tungsten, being so
hard a substance, would quickly wear away any other kind of die. The
thread formed was cut into proper lengths, bent the shape of a hair
pin and the ends fastened to clamps. Current was passed through the
hair pin in the presence of hydrogen gas and water vapor. The current
heated the hair pin, carbonized the organic binding material in it, the
carbon then combining with the moist hydrogen gas, leaving the tungsten
particles behind. These particles were sintered together by the heat,
forming the tungsten filament. Patents were applied for in various
countries, the one in the United States on July 6, 1905.
Public-domain text, read in full here on John Shaqi.
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