On Molecular and Microscopic Science, Volume 1 (of 2) — John Shaqi
On Molecular and Microscopic Science, Volume 1 (of 2)Somerville, Mary
History
On Molecular and Microscopic Science, Volume 1 (of 2)
Somerville, Mary
Matter -- Constitution; Microscopy; Natural history
Heat changes the position of the optical axes of crystals. When applied
to a crystal of sulphate of lime, the two optical axes gradually
approach to each other and at last coincide; if the heat be continued
and increased, the axes open again, but in a direction at right angles
to their former position. Thus the force of heat throws every molecule
in the body into correlative motion. The angles of all crystals that are
not of the octohedral group are changed by heat and vary with the
intensity; the difference between the length of the greatest and least
optic axes in such crystals diminishes as the temperature is raised,
increases when it is lowered, and is constant at a given heat. In
Iceland spar heat indirectly affects the doubly refracting power, for
the expansion of the crystal in the direction of its axis is accompanied
by contraction at right angles to it, which brings the crystal nearer to
the cubical form, and consequently diminishes its doubly refracting
power.
According to the researches of M. Angström, in crystals with different
axes of elasticity the velocity of the molecular vibrations is different
in different directions when they are heated. In rock crystal and
tourmaline the heat radiates from a surface cut parallel to the axis of
the crystal; in felspar the radiating surface is at right angles to the
symmetrical axis.
The optical axes of crystals are also affected by pressure. Doubly
refracting crystals with one principal axis acquire two when the
pressure is perpendicular to it. The new principal axis coincides with
the line of pressure or is at right angles to it according as the
crystal is positive or negative, that is, according as the extraordinary
ray is refracted to or from the optic axis of the crystal. The colours
produced by polarization are affected by compression and dilatation
according as the crystal is positive or negative.
Sir David Brewster is of opinion that all the properties of double
refraction and the gorgeous phenomena of polarization, whether by
crystals or produced in various substances permanently or transiently by
heat, cold, rapid cooling, compression, dilatation, and induration, are
wholly the result of the forces by which the atoms are held together;
but these phenomena may rather be said to depend upon a reciprocal
action between an irregular molecular structure and the agency of light
and heat: which indeed seems to be confirmed by the transit of these two
forces through right and left-handed quartz, for there is no reason to
believe that there is any difference in the form of the particles in
these two crystalline substances.
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