Scientific American Supplement, No. 324, March 18, 1882Various
Science
Scientific American Supplement, No. 324, March 18, 1882
Various
Science -- Periodicals
Now as to valency or atomicity, accepting the received atomic weights of
the elements, it is certain that there are at least four distinct types
of hydrogen compounds represented by ClH, OH_{2}, NH_{3}, CH_{4}. The
recognition of these types, and their relations to each other as
types, was one of the most important and best assured advances made in
theoretical chemistry. When we compare the formula of water with that of
hydrochloric acid, we find that there is twice as much hydrogen combined
with one atom of oxygen as there is combined with one atom of chlorine;
and in a great many other instances, we find that we can replace two
atoms of chlorine by one atom of oxygen, so that we get an idea of the
exchangeable value of these elements, and we say that one atom of oxygen
is worth two of chlorine, or is bivalent; similarly, nitrogen is said to
be trivalent. The meaning attached to the word "valency," is simply one
of interchangeability, just as we say a penny is worth two halfpennies
or four farthings. The question next arises, is the valency of an
element fixed or variable? If the word be defined as above, it is
absolutely certain that the valency varies. Thus, tin may be trivalent,
SnCl_{2}, or tetravalent, SnCl_{4}. Accordingly elements have been
classed as monads, dyads, triads, etc. The lecturer objected most
strongly to the word "atomicity;" he could not conceive of one atom
being more atomic than another; he could understand the atomicity of
a molecule or the equivalency of an atom, but not the atomicity of an
atom; the expression seemed to him complete nonsense. He next considered
the possibility of assigning a fixed limit to this valency or adicity of
an atom, and concluded that the adicity was not absolutely fixed, but
was fixed in relation to certain elements, e.g., C never combines with
more than four atoms of H; O never more than two atoms of H, etc. The
adicity of an element when combined with two or more elements is usually
higher than when combined with only one, e.g., NH_{3}, NH_{4}Cl. The
term "capacity of saturation," may be used as a synonym for adicity, if
care be taken to distinguish it from other kinds of saturation, such as
an acid with an alkali, etc. Adicity is, however, quite distinct from
combining force; the latter is indicated by the amount of heat evolved
in the combination.
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