Scientific American Supplement, No. 611, September 17, 1887Various
Science
Scientific American Supplement, No. 611, September 17, 1887
Various
Science -- Periodicals
The paper I have to lay before you describes the last product of the
brain of one of your past presidents--Alexander Angus Croll--in
connection with our industry. It may not be so well known to some of
the younger as it is to many of the older members of the Institute
that the fertile brain of Mr. Croll has done much for the improvement
and the extension of the gas industry. I consider that he has been the
most successful pioneer both in the cheapening and the purification of
gas--two elements without which our industry would progress but slowly
if at all; and the success which has crowned his efforts, to our
advantage, has reflected itself favorably on himself, showing by his
financial success that he has also been a good man of business. All
these are conditions which enhance the value of this paper. In the
present instance, I claim no other credit than that of being the
mouthpiece of Mr. Croll, whose assistant I was for ten of the busiest
and most important years of his eventful life; and having (with my son
Bruce) taken part in the experiments, I have been asked to describe
the process to the Institute.
The manufacture of sulphate of ammonia, as hitherto conducted, has
consisted either in bringing together sulphuric acid and ammoniacal
liquor or in distilling the liquor by external heat, or by the
introduction of steam, and bringing it into contact with the acid in
the form of gases and vapor of water. In either case a large volume of
noxious gases is given off, the chief of which, being sulphureted
hydrogen, has to be fixed by another method, in order to comply with
acts of Parliament for the prevention of nuisances.
By the processes hitherto used, we sometimes get only 11/4 tons of salts
to every ton of acid used; while in the more perfect forms of
apparatus, we may get 1-1/3 tons of salts. By Mr. Croll's process,
however, we get an increased yield of salts on the acid used, as
follows: The experiments were made with sulphuric acid of the specific
gravity of 1838, or nearly concentrated oil of vitriol; and the
quantity used was 8 ounces in each experiment. The ammoniacal liquor
was of uniform strength throughout all the experiments, being kept in
a corked jar; and the solution of sulphate of ammonia was passed
through filter paper before being crystallized. Thus we obtained a
white salt. In each experiment the solution of sulphate was divided
into four equal parts by weight, and one part filtered and
crystallized to dryness over a spirit lamp; the weight in each
experiment being as nearly as possible the same, or 31/4 oz. of salt to
2 oz. of acid--being in the proportion of 26 oz. of sulphate to 1 lb.
of acid, or 321/2 cwt. of salts to 20 cwt. of acid.
Public-domain text, read in full here on John Shaqi.
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