Scientific American Supplement, No. 717, September 28, 1889Various
Science
Scientific American Supplement, No. 717, September 28, 1889
Various
Science -- Periodicals
A number of these elements are placed side by side, with
non-conducting frames intervening, so as to form chambers through
which the hydrogen gas is passed along one side of the element and air
along the other.
This peculiar construction allows us to get a very large amount of
duty from a very small amount of platinum. One of the batteries before
you, consisting of seven elements, with a total effective surface of
half a square meter, contains 21/2 grammes of platinum leaf and 7
grammes of platinum black, a total of 91/2 grammes of platinum, and
produces a current of 2 amperes and 5 volts, or 10 watts, when the
outer resistance is properly adjusted. This current is equal to nearly
50 per cent. of the total energy obtainable from the hydrogen absorbed
in the battery.
In order to maintain a constant current, we have from time to time
(say once an hour) to interchange the gases, so as to counteract the
disturbing influence produced by the transport of the sulphuric acid
gas from one side of the diaphragm to the other. This operation can
easily be performed automatically by a commutator worked by a clock.
The water produced in the battery by the oxidation of the hydrogen is
carried off by the inert gas mixed with the hydrogen, and by the air,
of which we use a certain excess for this purpose. This is important,
as if the platinum black becomes wet, it loses its absorbing power for
the gases almost completely and stops the work of the battery. To
avoid this was in fact the great difficulty in designing a powerful
gas battery, and all previous constructions which employed the
electrolyte as a mobile liquid failed in consequence.
The results obtained by our battery are practically the same whether
pure oxygen and hydrogen or air and gases containing 25 per cent. of
hydrogen are used; but we found that the latter gases must be
practically free from carbonic oxide and hydrocarbons, which both
interfere very much with the absorbing power of the platinum black.
We had thus to find a cheap method of eliminating these two gases from
the producer gas, and converting them at the same time into their
equivalent of hydrogen. The processes hitherto known for this purpose,
viz., passing a mixture of such gases with steam over lime (which I
mentioned some time ago) or over oxide of iron or manganese, require
high temperatures, which render them expensive, and the latter do not
effect the reaction to a sufficient extent for our purpose.
We have succeeded in attaining our object at a temperature below that
at which the gases leave my producers, viz., at 350 deg. C. to 450 deg. C., by
passing the producer gases, still containing a considerable excess of
steam, over metallic nickel or cobalt. These metals have the
extraordinary property of decomposing almost completely, even at the
low temperature named, carbonic oxide into carbon and carbonic acid
and hydrocarbons into carbon and hydrogen.
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