Scientific American Supplement, No. 841, February 13, 1892 — John Shaqi
Scientific American Supplement, No. 841, February 13, 1892Various
Science
Scientific American Supplement, No. 841, February 13, 1892
Various
Science -- Periodicals
CHLORINE GAS AND SODA BY THE ELECTROLYTIC PROCESS.
The decomposition of a solution of common salt, and its conversion
into chlorine gas and caustic soda solution by means of an electric
current, has long been a study with electro-chemists. Experimentally
it has often been effected, but so far as we are aware, the success of
this method of production has never until now been demonstrated on a
sound commercial basis. The solution of this important industrial
problem is due to Mr. James Greenwood, who has been engaged in the
development of electro-chemical processes for many years. The outcome
of this is that Mr. Greenwood has now perfected an electrolytic
process for the direct production of caustic soda and chlorine, as
well as other chemical products, the operation of which we recently
inspected at Phoenix Wharf, Battersea, London. One of the special
features in connection with Mr. Greenwood's new departure is the novel
and ingenious method by which the electrolyzed products are separated,
and their recombination rendered impossible. This object is attained
by the use of a specially constructed diaphragm which is composed of a
series of V-shaped glass troughs, fitted in a frame within each other
with a small space between them, which is lightly packed with asbestos
fiber. Another important feature of the apparatus is a compound anode
which consists of carbon plates, with a metal core to increase the
conductivity. The anode is treated in a special manner so as to render
it non-porous and impervious to attack by the nascent chlorine evolved
on its surface. No anode appears ever to have been invented that is at
all suitable for working on a large scale, and the successful
introduction of this compound anode, therefore, constitutes a marked
advance in the apparatus used in electrolytic methods of production.
Public-domain text, read in full here on John Shaqi.
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