Bohr[8] has given a table setting out his theory of the way the
electrons are arranged in the various inert gases, each of which has
its outer ring as full as it will hold until there are other electrons
outside it. The helium atom, in its commoner form, he supposes to
contain two electrons moving in circles, each with the same total
quantum number, namely 1, as the minimum circle in hydrogen.
There is, however, as we saw, another form of helium, in which one
of the electrons moves in an eccentric orbit. In the next inert gas,
neon, there are 10 electrons, two in the inner ring and eight in
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the outer. The two in the inner ring, according to his table, remain
as in helium, but of the outer eight four are moving in circles and
four in ellipses. This and the other figures in his table apply, of
course, to the atom in its most compressed state, the state to which
it tends when it is let alone, the state corresponding to the minimum
circle in hydrogen. Argon, which comes next with 18 electrons, has
its two inner rings as in neon, but has eight electrons in a third
ring. Partly from spectroscopic considerations, partly on grounds of
stability, Bohr maintains that these eight outer electrons none of
them move in circles, but are divided into two groups of four, the
first group moving in orbits of very great eccentricity, the second
in less eccentric orbits. The first group of four will, at moments
penetrate inside the first ring. It is assumed that the two inner rings
are definitely completed as soon as we reach neon, but that the later
rings are not completed so quickly. For reasons which we explained
in Chapter III, the periods containing a great many elements in the
periodic table are best explained by assuming that the change from
one element to the next is not always in the outermost ring, but is
sometimes in the next ring, or even (in the case of the rare earths) in
the next but one. According to these principles, krypton, which is the
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element, and so has 18 more electrons than argon,
is not to have the whole 18 in its outer ring. Only 8 are to be
in the outer ring; the remaining 10 are added to the third ring,
which is to have eighteen electrons, six in orbits like one previous
group of four, six in orbits like the other previous group of four,
and six in circles. The eight outer electrons are again divided into
two groups of four, one group exceedingly eccentric (more so than any
in argon), and the other group somewhat less so. Passing to xenon, the
element in the periodic table, the first three rings
are as in krypton, the fourth ring has 18 electrons instead of
8, six in each of the groups that previously had four, and six in
orbits that are not circles, but have only a small eccentricity. As we
saw in connection with hydrogen in the previous chapter, as the total
quantum number increases, the number of possible orbits increases.
When the total quantum number is one, there is only one possibility
Public-domain text, read in full here on John Shaqi.
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