Several authors, M. Raveau in particular, have indeed given very
simple demonstrations of this law which are not based on
thermodynamics; but thermodynamics, which led to its discovery,
continues to give it its true scope. Moreover, it would not suffice
merely to determine quantitatively those laws of which it makes known
the general form. We must, if we wish to penetrate deeper into
details, particularize the hypothesis, and admit, for instance, with
Gibbs that we are dealing with perfect gases; while, thanks to
thermodynamics, we can constitute a complete theory of dissociation
which leads to formulas in complete accord with the numerical results
of the experiment. We can thus follow closely all questions concerning
the displacements of the equilibrium, and find a relation of the first
importance between the masses of the bodies which react in order to
constitute a system in equilibrium.
The statics thus constructed constitutes at the present day an
important edifice to be henceforth classed amongst historical
monuments. Some theorists even wish to go a step beyond. They have
attempted to begin by the same means a more complete study of those
systems whose state changes from one moment to another. This is,
moreover, a study which is necessary to complete satisfactorily the
study of equilibrium itself; for without it grave doubts would exist
as to the conditions of stability, and it alone can give their true
meaning to questions relating to displacements of equilibrium.
The problems with which we are thus confronted are singularly
difficult. M. Duhem has given us many excellent examples of the
fecundity of the method; but if thermodynamic statics may be
considered definitely founded, it cannot be said that the general
dynamics of systems, considered as the study of thermal movements and
variations, are yet as solidly established.
§ 5. ATOMISM
It may appear singularly paradoxical that, in a chapter devoted to
general views on the principles of physics, a few words should be
introduced on the atomic theories of matter.
Very often, in fact, what is called the physics of principles is set
in opposition to the hypotheses on the constitution of matter,
particularly to atomic theories. I have already said that, abandoning
the investigation of the unfathomable mystery of the constitution of
the Universe, some physicists think they may find, in certain general
principles, sufficient guides to conduct them across the physical
world. But I have also said, in examining the history of those
principles, that if they are to-day considered experimental truths,
independent of all theories relating to matter, they have, in fact,
nearly all been discovered by scholars who relied on molecular
hypotheses: and the question suggests itself whether this is mere
chance, or whether this chance may not be ordained by higher reasons.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account