Of the numerous alcohols possible, ethyl alcohol is the one ordinarily
sought and the easiest produced. This alcohol is represented by the
following chemical formula: C2H5-OH.
While glucose is the substance which may be easily transferred into
alcohol by fermentation, sucrose may also be used, providing it is
first changed into glucose or invert sugar. Even cellulose and starch
may be used after being transferred into reducing sugars.
The process of changing glucose into alcohol and carbon dioxide is
called fermentation and is accomplished by a minute organism. Sucrose
will not directly ferment, consequently it must first be changed into
glucose. This is usually accomplished by an enzyme which is secreted
by a ferment.
The following chemical formula will serve to show the steps necessary
to pass from sugar to an alcohol:
C12H22O11 (sucrose) + H2O (water) Presence of an
342 M. W.
enzyme --> Invert sugar
------------------------------------------
(C6H12O6 (dextrose) C6H12O6 (levulose))
180 M. W. 180 M. W.
--> C2H5-OH (ethyl alcohol) + 4CO2 (carbon dioxide)
184 (2 M. W.) 176 CM. W.
The theoretical yield then of alcohol from sucrose would be 53 per
cent and from invert sugar 51 per cent. In practice, however, this
yield would not be experienced on account of the yeast converting
some of the sugars into substances other than alcohol and carbon
dioxide. These will consist mostly of glycerine and succinic acid
and will amount to 4 or 5 per cent.
Since the working conditions determine to a very great extent the
yield of alcohol, it is obvious that a thoroughly efficient person
should be in charge of this work. In the selecting of cultures
for the fermenting, the manufacturer should use only the purest,
otherwise acetic acid and other foreign substances will be formed
during fermentation, thus decreasing the yield of the alcohol as well
as lowering its purity.
Where the percentage of sucrose and glucose of a molasses is known,
it is a simple matter to calculate the theoretical amount of alcohol
to be recovered and by knowing the efficiency of the factory, a factor
may be obtained which multiplied by the theoretical yield will give
the true amount of alcohol to be expected. In this manner it is easy
to determine the price that may be paid for any molasses.
The separation of the alcohol from the water and dirt (lees) is
accomplished in an apparatus termed a "still." In this the liquor is
heated by steam which causes the alcohol to evaporate. Since ethyl
alcohol boils at a temperature of 78° or a little higher, depending
upon the percentage present, it may be separated from the water and
impurities during the evaporation, and recovered from the coils of
the condenser in a fairly pure state.
Public-domain text, read in full here on John Shaqi.
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