The Principles of Leather ManufactureProcter, H. R. (Henry Richardson)
History
The Principles of Leather Manufacture
Procter, H. R. (Henry Richardson)
Leather
through a capillary tube.[30] The firmness of a jelly, which is often
important for commercial purposes, is frequently measured by Lipowitz’s
method, in which a slightly convex disc, conveniently of exactly 1 cm.
diameter, and cemented to the bottom of a thistle-head funnel tube, is
loaded gradually with mercury till it sinks in the jelly. The jelly (5
or 10 per cent.) should be allowed to set some hours before the test is
made.
[29] See Pascheles, ‘Versuche über Quellung,’ Archiv für ges. Path.,
Bd. 71.
[30] See Prollius, Ding. Polyt. Journ., ccxlix. p. 425, who employs a
1 per cent. solution; also Stützer, Zeit. Ann. Ch., xxxi. pp. 501-15.
Solutions of gelatin from skin and bone are powerfully lævorotatory to
polarised light. At 30° C. (A)_{D} = -130°, but temperature and the
reaction of the solution have much influence on the value found.
Gelatin is precipitated from aqueous solution by the addition of strong
alcohol and concentrated solutions of ammonium sulphate and some other
salts. Many other colloid bodies such as dextrin and gums behave
similarly. In the absence of these substances, precipitation by alcohol
may be utilised for the technical analysis of gelatins and glues,
printers’ roller compositions and gelatin confectionery. 25 c.c. of the
gelatinous solution, which is preferably of about 10 per cent., is
placed in a small beaker tared together with a glass stirring rod, and
thrice its volume of absolute alcohol added. On stirring, the gelatin
sets firmly on the rod and sides of the beaker, and may be washed with
dilute alcohol or even with cold water, dried and weighed. A very pure
French gelatin gave 98·6 per cent., while a common bone-glue only
yielded about 60 per cent. precipitate. Absolute alcohol withdraws water
from gelatin-jelly, leaving a horny mass. Gelatin may also be
precipitated completely by saturating its solution with sodium chloride,
and then acidifying slightly with sulphuric or hydrochloric acid; and
masses of jelly become hardened in acidified salt solution as in
alcohol, though a neutral solution has little effect. The cause of this
is difficult of explanation, but its bearing on the pickling of
sheep-skins (p. 89) and the production of white leather (p. 186) is
obvious.
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