Volcanoes: What They are and What They Teach — John Shaqi
Volcanoes: What They are and What They TeachJudd, John W. (John Wesley)
Science
Volcanoes: What They are and What They Teach
Judd, John W. (John Wesley)
Volcanoes
What is the nature of the liquids which are thus imprisoned in these
cavities contained in the crystals of lavas and granites? Careful
experiments have given a conclusive answer to this question. In many
cases the liquid is water, usually containing considerable quantities
of saline matter dissolved in it. Sometimes the saline matters are
present in such abundance that they cannot all pass into solution, but
crystallise out, as in fig. 7--Nos. 3, 4, 5--where cubic crystals of
the chlorides of sodium and potassium are seen floating in the liquid;
in other cases the liquid is a hydrocarbon like the mineral oil which
is present in great abundance in deep-seated rocks in many parts of the
globe. But in some other cases the liquid contained in the cavities
of crystals is found to be one which could scarcely be anticipated
to occur under such circumstances--the gas known as carbonic add,
which under extreme pressure can be reduced to a liquid condition. In
cavities containing liquefied carbonic acid, if the rock be warmed up
to 86° or 90° Fahrenheit the bubble suddenly vanishes, sometimes with
an appearance like ebullition or boiling, as represented in fig. 9.
Now the temperature which we have indicated is the 'critical point' of
carbonic acid, and above that temperature it cannot exist in a liquid
condition, however great may be the pressure to which it is subjected.
The liquid has been converted into a gas which completely fills the
cavity. The carbonic acid in the cavities of crystals has frequently
been isolated and its nature placed beyond doubt by spectroscopic and
ordinary chemical tests.
The presence of these liquids in the cavities of crystals clearly
proves that the latter must have been formed under enormous pressure--a
pressure sufficiently great to reduce, not only steam, but also
volatile hydrocarbons and even gaseous carbonic acid, to the bulk of a
liquid.
[Illustration: Fig. 9.--Cavity in Crystal containing Carbonic-Acid Gas
at a temperature of 86° F., and passing from the liquid to the gaseous
condition.]
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