A History of Science — Volume 5Williams, Henry Smith
History
A History of Science — Volume 5
Williams, Henry Smith
Science -- History
As we said a moment ago, radium appears to be an elementary substance,
as shown by its spark-spectrum being different from that of any other
known substance--the determinative test as fixed by the International
Chemical Congress. A particle of radium free from impurities should,
therefore, according to the conventional conception of an element,
remain unchanged and unchangeable. If any such change did actually take
place it would mean that the conception of the Daltonian atom as
the ultimate particle of matter is definitively challenged from a new
direction. This is precisely what has taken place. In July of 1903 Sir
William Ramsay and Mr. Soddy, in making some experiments with radium,
saw produced, apparently from radium emanations, another quite different
and distinct substance, the element helium. The report of such a
revolutionary phenomenon was naturally made with scientific caution.
Though the observation seemed to prove the actual transformation of one
element into another, Professor Ramsay himself was by no means ready to
declare the absolute certainty of this. Yet the presumption in favor
of this interpretation of the observed phenomena is very strong; and so
cautious a reasoner as Professor Rutherford has declared recently that
"there can be no doubt that helium is derived from the emanations of
radium in consequence of changes of some kind occurring in it."*6*
"In order to explain the presence of helium in radium on ordinary
chemical lines," says Professor Rutherford, "it has been suggested that
radium is not a true element, but a molecular compound of helium with
some substance known or unknown. The helium compound gradually breaks
down, giving rise to the helium observed. It is at once obvious that
this postulated helium compound is of an entirely different character to
any other compound previously observed in chemistry. Weight for weight,
it emits during its change an amount of energy at least one million
times greater than any molecular compound known. In addition, it must
be supposed that the rate of breaking up of the helium compound is
independent of great ranges of temperature--a result never before
observed in any molecular change. The helium compound in its breaking
up must give rise to the peculiar radiations and also pass through the
successive radio-active change observed in radium.... On the other
hand, radium, as far as it has been examined, has fulfilled every
test required of an element. It has a well-marked and characteristic
spectrum, and there is no reason to suppose that it is not an element in
the ordinarily accepted sense of the term."*7*
THE SOURCE OF ENERGY OF RADIO-ACTIVITY
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