A Manual of Photographic Chemistry, Including the Practice of the Collodion ProcessHardwich, T. Frederick
Science
A Manual of Photographic Chemistry, Including the Practice of the Collodion Process
Hardwich, T. Frederick
Photographic chemistry; Photography
In exemplifying further the importance of distinguishing between visual
and actinic rays of light, we may observe that if the two were in all
respects the same. Photography must cease to exist as an Art. It would
be impossible to make use of the more sensitive chemical preparations
from the difficulties which would attend the previous preparation and
subsequent development of the plates. These operations are now conducted
in what is termed a dark room; but it is dark only in a _Photographic_
sense, being illuminated by means of yellow light, which, whilst it
enables the operator easily to watch the progress of the work, produces
no injurious effect upon the sensitive surfaces. If the windows of the
room were glazed with _blue_ in place of yellow glass, then it would
be strictly a "dark room," but one altogether unfitted for the purpose
intended.
Another point connected with the same subject and worthy of note
is--the extent to which the sensibility of the Photographic compounds is
influenced by atmospheric conditions not visibly interfering with the
_brightness_ of the light. It is natural to suppose that those days on
which the sun's rays are the most powerful would be the best for rapid
impression, but such is not by any means the case. If the light is at all
of a yellow cast, however bright it may be, its actinic power will be
small.
It will also be often observed in working towards the evening, that a
sudden diminution of sensibility in the plates begins to be perceptible at
a time when but little difference can be detected in the brilliancy of the
light; the setting sun has sunk behind a golden cloud, and all chemical
action is soon at an end.
In the same manner is explained the difficulty of obtaining Photographs
in the glowing light of tropical climates; the superiority Of the early
months of spring over those of the midsummer; of the morning sun to that
of the afternoon, etc. April and May are usually considered the best
months for rapid impression in this country; but the light continues good
until the end of July. In August and September a longer exposure of the
plates will be required.
THE SUPERIOR SENSIBILITY OF BROMIDE OF SILVER TO COLOURED LIGHT.
In copying the Solar Spectrum alternately upon a surface of Iodide and
Bromide of Silver, we notice a difference in the Photographic properties
of these two salts. The latter is affected more extensively, to a point
lower in the spectrum, than the former. In the case of the Iodide of
Silver, the action ceases in the Blue space; but with the Bromide it
reaches to the Green. This is shown in the following diagrams, which are
drawn from the observations of Mr. Crookes ('Photographic Journal,' vol.
i. p. 100):--
[Illustration: Fig. 1. Fig. 2. Fig. 3.]
Fig. 1 represents the chemical spectrum on Bromide of Silver; fig. 2, the
same upon Iodide of Silver; and fig. 3, the visible spectrum.
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