_Preparation of Pyroxyline._--If, instead of treating Cotton with Nitric Acid, a mixture of Nitric and Sulphuric Acids in certain proportions be used, the effect is peculiar. The fibres contract slightly, but undergo no other visible alteration. Hence we are at first disposed to think the mixed Acids ineffectual. This idea however is not correct, since on making the experiment the properties of the cotton are found to be changed. Its weight has increased by more than one-half; it has become soluble in various liquids, such as Acetic Ether, Ether and Alcohol, etc., and, what is more remarkable, it no longer burns in the air quietly, but explodes on the application of flame with greater or less violence. This change of properties clearly shows, that although the fibrous structure of the material is unaffected, it is no longer the same substance, and consequently chemists have assigned it a different name, viz. Pyroxyline. To produce the peculiar change by which Cotton is converted into Pyroxyline, both Nitric and Sulphuric Acids are, as a rule, required; but of the two the former is the most important. On analyzing Pyroxyline, Nitric Acid, or a body analogous to it, is detected in considerable quantity, but not Sulphuric Acid. The latter Acid, in fact, serves but a temporary purpose, viz. to prevent the Nitric Acid from dissolving the pyroxyline, which it would be liable to do if employed alone. The Sulphuric Acid prevents the solution by removing water from the Nitric Acid, and so producing a higher degree of concentration; Pyroxyline, although soluble in a dilute, is not so in the strong Acid, and hence it is preserved. The property possessed by Oil of Vitriol of removing water from other bodies, is one with which it is well to be acquainted. A simple experiment will serve to illustrate it. Let a small vessel of any kind be filled to about two-thirds with Oil of Vitriol, and set aside for a few days; at the end of that time, and especially if the atmosphere be damp, it will have absorbed sufficient moisture to cause it to flow over the edge. Now even the strongest reagents employed in chemistry contain, almost invariably, water in greater or lesser quantity. Pure Anhydrous Nitric Acid is a white, solid substance; Hydrochloric Acid is a gas: and the liquids sold under those names are merely solutions. The effect then of mixing strong Oil of Vitriol with aqueous Nitric Acid is to remove water in proportion to the amount used, and to produce a liquid containing Nitric Acid in a high state of concentration, and Sulphuric Acid more or less diluted. This liquid is the Nitro-Sulphuric Acid employed in the preparation of Pyroxyline.