The principle of polarity, therefore, aided by the subsidiary conditions
of quantivalence, atomicity, and isomerism, gives the clue to the
construction of the inorganic world out of some seventy elementary
substances. Of the substances thus formed, whether of molecules or
of combinations of molecules, some are stable and some unstable. As
a rule the simpler combinations are the most stable, and instability
increases with complexity. Thus the diamond, which is merely a crystal
of pure carbon, is very hard and indestructible; while dynamite, or
nitro-glycerine, which is a very complex compound, explodes at a touch.
The stability of a substance depends partly on the stable structure of
its component elements, and partly on their mutual affinity being strong
enough to keep them together in presence of the attractions of other
outside elements, which, in the case of most natural substances at the
surface of the earth, consist principally of air and water. Thus, the
rocks, earths, metallic oxides, water, carbonic dioxide, and nitrogen
are extremely stable, and resist decomposition, or chemical union with
other substances, with great energy. With regard to all substances this
law holds good, that the tendency is to fall back from a less stable to
a more stable condition, and that such a falling back is always attended
with an evolution of heat; while, on the other hand, heat is always
absorbed and disappears whenever the elements of a more stable substance
are made to enter into a less stable condition. Thus, when wood burns,
there is a falling back from a substance unstable, on account of its
affinity for the oxygen in the air, into the stable products, carbonic
dioxide and water, and the heat evolved is the effect of this fall.
As the tendency of all changes is towards stability we arrive at the
following law, which is one of the most recent generalisations of modern
chemistry: In all cases of chemical change the tendency is to those
products whose formation will determine the greatest evolution of heat.
This, however, does not imply that the tendency may not be overcome and
unstable products formed, for just as a weight may be lifted against
the force of gravity, so may the chemical tendency be overcome by a
sufficient energy acting against it. Heat is the principal means of
supplying this energy, and by increasing it sufficiently not only
are molecules drawn apart and most solids converted into fluids and
finally into gases, but there is reason to believe that at extremely
high temperatures, such as may prevail in the sun, all matter would be
resolved into isolated or dissociated atoms. Thus, water at a temperature
of 1,200° is resolved into a mixture of oxygen and hydrogen atoms no
longer chemically united into water-molecules; and iodine-vapour, which
below 700° degrees consists of molecules of two atoms, above that
temperature consists of single atoms only.
Public-domain text, read in full here on John Shaqi.
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