A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
Manganese Oxygen
Protoxide 100 + 28 -- buff; soluble in acids.
Intermediate oxide -- + 42 -- brown; insoluble.
Deutoxide -- + 56 -- black; insoluble.
It may be proper to subjoin the results of others, who have
investigated the oxides of manganese. Bergman finds 3 oxides,
containing 100 metal + 25, 35, and 66.6 oxygen; Dr. John finds 3
oxides, containing 100 metal + 15, 25, and 40 oxygen: Berzelius finds
5 oxides, containing 100 metal + 7, 14, 28, 42, and 56 oxygen; and
Davy finds 2 oxides, containing 100 metal + 26.6, and 39.9 oxygen,
respectively.
23. _Oxides of chromium._
There appear to be at least two oxides of chromium, one or other of
which is found in combination with the oxides of lead or iron, but
hitherto so very sparingly that few chemists have had an opportunity of
investigating the proportions of chrome and oxygen, in the oxides of
chromium. The chief sources for information on this subject, are essays
by Vauquelin, An. de Chimie, VOL. 25 and 70; by Tassaert, _ibid._ 31;
by Mussin Puschin, _ibid._ 32; by Godon, _ibid._ 53; by Laugier _ibid._
78, and by Berzelius, Annal. of Philosophy, 3.
The oxides of chromium, as might be supposed, are distinguished for the
colours which they possess and impart to the compounds into which they
enter. One of the oxides is green; it gives colour to the emerald. The
other is yellow, dissolved in water, but deep red when crystallized,
and possesses the characters of an acid; it unites with alkalies,
earths, and metallic oxides; it was first found in Siberia, in
combination with the oxide of lead, a salt now denominated _chromate_
of lead, of a splendid yellow colour, inclining to orange or red.
Since then, the chromate of iron, has been found in France, America,
and Siberia, with a prospect of greater abundance.
In order to investigate the weight of the atom of chromic acid, it is
necessary to attend to such of the chromates as have been carefully
examined. The chromates of potash, barytes, lead, iron, and mercury,
are those with which we are best acquainted.
Vauquelin has given us the components of the native chromate of lead
by analysis, and those of the artificial chromate by synthesis; the
results do not accord very nearly: for, according to the analysis
corrected by the modern science,
Chromate of lead = 62 acid + 97 oxide
By synth. chromate of lead = 57½ -- + 97 --
Berzelius however, has more lately given us the results of his
experience, both analytical, and synthetical; and he finds both to give
chromate of lead nearly = 44 acid + 97 oxide.
Chromate of barytes (Vauq.) = 47.8 acid + 68 barytes
Ditto (Berz.) = 44 -- + 68 --
Native chromate of iron (Vauq.) = 45 acid + 35½ oxide
Ditto (Laugier) = 55 -- + 35½ --
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account