A new system of chemical philosophy, Volume 2, Part 1Dalton, John
Science
A new system of chemical philosophy, Volume 2, Part 1
Dalton, John
Atomic theory; Chemistry, Inorganic
The sulphurets exhibit a very important class of combinations of two
elements. Many of the metals are found chiefly in the state of native
sulphurets, and are extracted by particular processes. Artificial
combinations of sulphur and the metals, and of sulphur and the earths
and alkalies are commonly practised, and are found useful in chemical
investigations. The alkaline and earthy sulphurets will scarcely be
allowed perhaps to be combinations of _two elements_ only; but their
analogy with the other compounds is such as to induce us to treat of
them under this head, especially as they are agents occasionally in
the formation of metallic sulphurets, and these cannot be so well
understood without some knowledge of the other. For like reasons
the compounds of three elements, sulphur, metal, and oxygen, called
sulphuretted oxides, and sulphuretted sulphites, and those of four
elements, sulphur, metal, oxygen and hydrogen, called hydrosulphurets,
may be considered at the same time, having an intimate relation with
the sulphurets strictly so called, or the compounds formed with sulphur
and the undecompounded bodies.
Sulphur may be combined with the earths, alkalies and metals, by heat,
of various degrees according to the nature of the subjects. The union
is attended in many cases with a glowing ignition, indicating the
evolution of heat. The metallic oxides and sulphur when heated together
commonly produce a sulphuret of the metal, whilst the oxygen escapes
with part of the redundant sulphur in the form of sulphurous acid, and
the rest of the sulphur sublimes.
In the humid way sulphur may be combined with earths, alkalies, and
metals, by means of sulphuretted hydrogen, hydrosulphurets (that is,
sulphuretted hydrogen united to other alkaline or earthy bases), and
hydroguretted sulphurets (a name given to certain earthy and alkaline
sulphurets formed mostly by boiling mixtures of the respective bases
and sulphur in water.) The sulphuretted hydrogen may be used in
this state of gas or combined with water; the hydrosulphurets and
hydroguretted sulphurets are best applied in their watery solutions.
The metals are to be used in this case in the state of salts, that is,
oxides united to acids, and in solution; or their oxides may in some
instances be precipitated previously to the addition of the sulphur
compound; the alkalies and earths are sometimes directly sulphurized in
the state of hydrates, and at other times by double affinity, in the
state of salts or combined with acids. The phenomena in the case of
sulphurets formed in the humid way, are various and often complicated,
and the true results are not always to be obtained without considerable
difficulty and uncertainty.
1. _Sulphurets of lime._
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