A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations — John Shaqi
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
The salts of potash, with the exception of the borate and the
phosphate, color the flame of a rich violet hue. This color is best
discovered in the outer flame of the blowpipe, as is the case with all
the other colors. The flame should be a small one, with a lamp having
a small wick, while the orifice of the blowpipe must be quite small.
These experiments should likewise be made in a dark room, so that the
colors may be discerned with the greatest ease. In investigating with
potash for the discernment of color, it should be borne in mind that
the least quantity of soda will entirely destroy the violet color of
the potash, by the substitution of its own strong yellow color. If
there be not more than the two hundredth part of soda, the violet
reaction of the potash will be destroyed. This is likewise the case
with the presence of lithia, for its peculiar red color will destroy
the violet of the potash. Therefore in making investigations with the
silicates which contain potash, the violet color of the latter can
only be discerned when they are free from soda and lithia.
B. THE BLUE COLOR.
(_a._) _The Chloride of Copper._--Any of the chlorides produce a blue
color in the blowpipe flame, or any salt which contains chlorine will
show the blue tint, as the color in this case is referable to the
chlorine itself. There are, however, some chlorides which, in
consequence of the peculiar reactions of their bases, will not produce
the blue color, although in these cases the blue of the chlorine will
be very likely to blend itself with the color produced by the base.
The chloride of copper communicates an intense blue to the flame, when
fused on the platinum wire. If the heat be continued until the
chlorine is driven off, then the greenish hue of the oxide of copper
will be discerned.
(_b._) _Lead._--Metallic lead communicates to the flame a pale blue
color. The oxide reacts in the same manner. The lead-salts, whose
acids do not interfere with the color, impart also a fine blue to the
flame, either in the platina forceps, or the crooked wire.
(_c._) _Bromide of Copper._--This salt colors the flame of a
bluish-green color, but when the bromine is driven off, then we have
the green of the oxide of copper.
(_d._) _Antimony._--This metal imparts a blue color to the blowpipe
flame, but if the metal is in too small a quantity, then the color is
a brilliant white. If antimony is fused on charcoal, the fused metal
gives a blue color. The white sublimate which surrounds the fused
metal, being subjected to the flame of oxidation, disappears from the
charcoal with a bluish-green color.
(_e._) _Selenium._--If fused in the flame of oxidation, it imparts to
the flame a deep blue color. The incrustation upon charcoal gives to
the flame the same rich color.
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