A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations — John Shaqi
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic CombinationsAnonymous
Science
A System of Instruction in the Practical Use of the Blowpipe: Being A Graduated Course Of Analysis For The Use Of Students And All Those Engaged In The Examination Of Metallic Combinations
Anonymous
Blowpipe
(_f._) _Arsenic._--The arseniates and metallic arsenic itself impart
to the blowpipe flame a fine blue color, provided that there is no
other body present which may have a tendency to color the flame with
its characteristic hue. The sublimate of arsenious acid which
surrounds the assay, will give the same blue flame, when dissipated by
the oxidation flame. The platinum forceps will answer for the
exhibition of the color of arsenic, even though the salts be
arseniates, whose bases possess the property of imparting their
peculiar color to the flame, such as the arseniate of lime.
C. THE GREEN COLOR.
(_a._) _Ammonia._--The salts of ammonia, when heated before the
blowpipe, and just upon the point of disappearing, impart to the flame
a feeble though dark green color. This color, however, can only be
discerned in a dark room.
(_b._) _Boracic Acid._--If any one of the borates is mixed with two
parts of a flux composed of one part of pulverized fluorspar, and four
and a half parts of bisulphate of potash, and after being melted, is
put upon the coil of a platinum wire, and held at the point of the
blue flame, soon after fusion takes place a dark green color is
discerned, but it is not of long duration. The above process is that
recommended by Dr. Turner. The green color of the borates may be
readily seen by dipping them, previously moistened with sulphuric
acid, into the upper part of the blue flame, when the color can be
readily discerned. If soda be present, then the rich green of the
boracic acid is marred by the yellow of the soda. Borax, or the
biborate of soda (NaO, 2BO_{3}) may be used for this latter reaction,
but if it be moistened with sulphuric acid, the green of the boracic
acid can then be seen. If the borates, or minerals which contain
boracic acid, are fused on charcoal with carbonate of potash, then
moistened with sulphuric acid and alcohol, then the bright green of
the boracic acid is produced, even if the mineral contains but a
minute portion of the boracic acid.
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