A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
This disadvantage is got rid of by making the mouth of the jet the lower
limit, or, in other words, allowing the instrument to empty itself.
There are two forms of such pipettes; in the one generally recommended
in Gay-Lussac's silver assay (the last shown in fig. 29) the nose is
replaced by a jet. This is most conveniently filled by stopping the jet
with the finger, and allowing the liquid to flow in a fine stream into
the neck until the pipette is filled, and then working as just
described. The other form is the one in general use; in fact, a long
nose to a pipette is so convenient that it may almost be said to be
necessary. But the accuracy is slightly diminished; a long narrow tube
makes a poor measuring instrument because of the amount of liquid it
finally retains. A defect possessed by both forms is the retention of a
drop of varying size in the nozzle. Whatever method is adopted for
removing this drop must be always adhered to. The most convenient form
is the one last described, and the most useful sizes are 100 c.c., 50
c.c., 20 c.c., 10 c.c., and 5 c.c. Ten c.c. pipettes graduated into
tenths of a cubic centimetre are very useful: those are best in which
the graduation stops short of the bottom.
All measurements should be made at the ordinary temperature; and, before
being used, the pipette should be rinsed out with a cubic centimetre or
so of the solution to be measured. After using, it should be washed out
with water.
~Burettes~ differ mainly from pipettes in having the flow of liquid
controlled from below instead of from above. The best form is that known
as Mohr's, one kind of which is provided with a glass stopcock, while
the other has a piece of india-rubber tube compressed by a clip. The
latter cannot be used for solutions of permanganate of potash or of
iodine, or of any substance which acts on india-rubber; but in other
respects there is little to choose between the two kinds. A burette
delivering 100 c.c., and graduated into fifths (_i.e._, each division =
0.2 c.c.), is a very convenient size. For some kinds of work, 50 c.c.
divided into tenths (_i.e._, each division = 0.1 c.c.) may be selected.
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