A text-book of assaying : $b for the use of those connected with mines.Beringer, C. (Cornelius)
Science
A text-book of assaying : $b for the use of those connected with mines.
Beringer, C. (Cornelius)
Assaying
~Acetic Acid~, H[=A=c] or C_{2}H_{4}O_{2}. (sp. gr. 1.044, containing 33
per cent. real acid).--An organic acid, forming a class of salts,
acetates, which are for the most part soluble in water, and which, on
ignition, leave the oxide or carbonate of the metal. It is almost always
used in those cases where mineral acids are objectionable. To convert,
for example, a solution of a substance in hydrochloric acid into a
solution of the same in acetic acid, alkali should be added in excess
and then acetic acid. Many compounds are insoluble in acetic acid, which
are soluble in mineral acids, such as ferric phosphate, ferric arsenate,
zinc sulphide, calcium oxalate, &c., so that the use of acetic acid is
valuable in some separations. The commercial acid is strong enough for
most purposes, and is used without dilution.
~"Aqua Regia"~ is a mixture of 1 part by measure of nitric acid and 3
parts of hydrochloric acid. The acids react forming what is practically
a solution of chlorine.[6] The mixture is best made when wanted, and is
chiefly used for the solution of gold and platinum and for "opening up"
sulphides. When solutions in aqua regia are evaporated, chlorides are
left.
~Bromine~, Br. (sp. gr. 3.0). Practically pure bromine.--It is a heavy
reddish-brown liquid and very volatile. It boils at 60° C., and,
consequently, must be kept in a cool place. It gives off brown
irritating vapours, which render its use very objectionable. Generally
it answers the same purpose as aqua regia, and is employed where the
addition of nitric acid to a solution has to be specially avoided. It is
also used for dissolving metals only from ores which contain metallic
oxides not desired in the solution.
~"Bromine Water"~ is simply bromine shaken up with water till no more is
dissolved.
~Carbonic Acid~, CO_{2}.--A heavy gas, somewhat soluble in water; it is
mainly used for providing an atmosphere in which substances may be
dissolved, titrated, &c., without fear of oxidation. It is also used in
titrating arsenic assays with "iodine" when a feeble acid is required
to prevent the absorption of iodine by the alkaline carbonate. It is
prepared when wanted in solution, by adding a gram or so of bicarbonate
of soda and then as much acid as will decompose the bicarbonate
mentioned. When a quantity of the gas is wanted, it is prepared, in an
apparatus like that used for sulphuretted hydrogen, by acting on
fragments of marble or limestone with dilute hydrochloric acid.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account