A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
Various attempts have been made from time to time to remove from the
waste liquors the soluble matter derived from the esparto by the
addition of lime. This throws it down as a very voluminous precipitate,
exceeding difficult of filtration. The filtrate contains only caustic
soda. The difficulties of removal of the precipitate, however, are
almost insurmountable. The usual method of disposing of the liquor
is to evaporate it to dryness and ignite it, as will be subsequently
described under the head of “Soda Recovery,” Chapter XII.
_Straw._—Straw very closely resembles esparto in its chemical
constitution; it is, however, more highly lignified, and for this
reason (see p. 63) requires a more drastic treatment for its
resolution. It is therefore usual to treat straw with rather larger
quantities of caustic, and generally at high pressures. It is possible,
however, to resolve it at 5–10 lbs. pressure, but the resulting
pulp is more difficult to bleach, and can only be used for inferior
kinds of paper. In treating straw for use in high-class paper, it is
necessary to boil under such conditions that even the knots, which are
much less readily attacked, shall be so far disintegrated that they
may be bleached with a moderate quantity of bleaching powder. Such a
treatment, on the other hand, involves a diminished yield of pulp, and
at the same time a somewhat weakened fibre.
The kinds of straw in general use are wheat, oat, rye, and barley; the
two first constituting the bulk of the raw material, at least in this
country. Some idea of the composition of straw may be gathered from the
analyses given on p. 59.
It will be seen that the amount of cellulose is quite as high as in
esparto, but for the reasons above given and from the fact that a
large proportion of the cellulose consists of cellular tissue (see
Figs. 12 and 13), which is easily attacked by soda and readily passes
through the meshes of the {99} drum-washers and the wire-cloth of the
presse-pâte and paper machine, the yield obtained in practice falls
considerably below that from esparto.
In addition to the numbers already quoted on p. 59, the following
results of analyses made from time to time by the authors, may be
interesting. The percentages are calculated on the absolutely dry
material.
Cellulose
per cent.
Oat Straw 52·0
Oat Straw 53·5
Wheat Straw 49·6
Rye Straw (Foreign) 53·0
Oat Straw (Foreign) 46·5
Wheat Straw (Foreign) 50·2
The yield of pulp is greatly influenced by the conditions under which
it is obtained; high pressures and temperatures exerting considerable
influence on the result. This is probably the case with straw more than
any other fibre, on account of the physical and chemical nature of
the cellulose. It is doubtful whether much more than 35 per cent. is
actually obtained in practice.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account