A Text-book of Paper-makingCross, C. F. (Charles Frederick)
Science
A Text-book of Paper-making
Cross, C. F. (Charles Frederick)
Paper industry; Papermaking
A method of treating straw is sometimes adopted which produces a pulp
of higher quality than is obtainable by the ordinary method. The washed
pulp is mixed in a chest provided with stirrers, with a large quantity
of water, and is then pumped into another chest placed at a higher
level, from which it flows between a pair of hard granite millstones,
the surfaces of which are cut into radial grooves. The stones are fixed
horizontally, and are made to revolve at a very rapid rate. During the
passage of the pulp through the stones, the knots, weeds, and other
hard portions of the {102} straw which may have resisted the action
of the alkali are reduced to a fine state of division, and are thus
more readily acted upon in the subsequent operation of bleaching. The
degree of fineness to which the pulp is reduced can be determined by
regulating its flow and the distance between the stones. Pulp produced
in this way is of a very even character, and is comparatively free from
unbleached particles.
Within the last few years a process of treating straw has been
introduced which, on account of the high quality of the pulp produced,
has attracted considerable attention from paper-makers. It consists
in exposing pulp obtained in the usual way by the action of caustic
soda to the action of chlorine gas. The method was patented in England
on March 3rd, 1880 (No. 938), by Friedrich Carl Glaser. The amount of
soda in the preliminary boiling is reduced much below that necessary
for perfect pulping, the result being that the cellulose is much less
liable to be destroyed, and thus a greater yield is obtained. The pulp
is thoroughly washed and partially freed from moisture in a centrifugal
machine until only about 70 per cent. remains. The partially dried
pulp is then exposed in leaden or stone chambers for some hours in an
atmosphere of chlorine, produced by the action of hydrochloric acid
upon manganese dioxide. By the action of the chlorine, those portions
of the straw which have been but imperfectly acted upon by the caustic
soda in the boiling process are completely disintegrated, or, rather,
are rendered more susceptible to the action of the bleaching liquor
employed subsequently. The consequence is that when bleaching liquor
is added, the whole of the straw is rapidly reduced to the state of
pure cellulose, and the finished product is remarkably free from
anything like unbleached portions. Owing to the fact that the action
of the caustic is minimised, a considerable proportion of the more
easily degraded cellulose survives, and the yield of pulp is thereby
increased. The process is, however, necessarily expensive. The action
of the chlorine will be readily understood by a reference to p. 19.
{103}
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