A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
In order to make clear to those readers who have not studied modern
organic chemistry, what we do know on the subject, a few words of
introduction will be necessary. All organic compounds contain carbon,
in combination with hydrogen, and very frequently also with oxygen,
nitrogen, and other elements. A single atom of carbon is able to
combine with 4 atoms of hydrogen, as it does to form marsh gas, or
methyl hydride, CH_{4}. Other elements may be substituted for the
hydrogen; for instance, if we replace 3 of the hydrogen atoms with
chlorine, we obtain chloroform, CHCl_{3}. Again an atom of oxygen may
be inserted between the carbon atom and one of the hydrogen atoms,
producing methyl hydroxide or wood spirit. The group CH_{3} is called
methyl, and we may substitute in wood spirit this entire methyl group
for one of the atoms of hydrogen, when we shall have ordinary alcohol,
C_{2}H_{5}OH. This building-up process may be repeated almost _ad
infinitum_, producing a whole series of alcohols of higher and higher
boiling point as the atoms of carbon become more numerous. Again, if
in wood spirit we substitute an atom of oxygen for 2 of the remaining
atoms of hydrogen we obtain formic acid, CHO.OH, the first of a long
series of acids, of which the second, corresponding to ordinary
alcohol, is acetic acid, and the highest members, such as stearic acid,
C_{18}H_{35}O.OH, are solid fats. Hence the whole series are commonly
called the fatty acids. A few structural formulæ will serve to make
these points clearer, but it may be well to say that such formulæ must
be taken simply as indicating the order in which the different atoms
are united, and in no sense their actual position in space. The atoms
in a molecule are held together by attractions and are in continual
motion, so that they are more comparable to the planets of the solar
system than to a rigid shape.
_Methyl Hydride._ _Methyl Alcohol._ _Common Alcohol._
H H H H
│ │ │ │
H──C──H H──C──O──H H──C──C──O──H
│ │ │ │
H H H H
_Chloroform._ _Formic Acid._ _Acetic Acid._
Cl O H O
│ ║ │ ║
H──C──Cl H──C──O──H H──C──C──O──H
│ │
Cl H
In benzene, C_{6}H_{6} we have a compound of another type.
There is reason to think that the carbon atoms in this case
are united in a ring, as shown,
H H H
│ │ │
C──C══C
║ │
C──C══C
│ │ │
H H H
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