A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.Procter, H. R. (Henry Richardson)
Science
A Text-book of Tanning: A treatise on the conversion of skins into leather, both practical and theoretical.
Procter, H. R. (Henry Richardson)
Tanning
It is not, however, generally necessary to resort to so elaborate a
process merely to distinguish the class to which tannins belong. The
tannin, or its infusion, may be simply boiled with dilute hydrochloric
acid for some time, replacing the acid lost by evaporation. The
solution is diluted to 50 _c.c._ and allowed to cool. Ellagic acid and
phlobaphenes may separate, and must be filtered off. If the precipitate
is pale, it is probably ellagic acid, and maybe recognised by the
nitric acid test. If red, it probably consists of phlobaphenes, and may
be treated with cold alcohol, in which phlobaphenes are freely soluble,
but ellagic acid very little. The ellagic acid will therefore be left
on the filter if present in any quantity, while the alcoholic solution
may be precipitated by the addition of water, and the phlobaphenes
further examined by treatment with potash.
Gallic Acid.--_Dioxysalicylic acid_, C_{6}H_{2}(OH)_{3}CO.OH, exists
ready formed in some plants, and is a product of the fermentation
of gallotannic acid under the influence of the nitrogenous ferment,
pectase, or of its decomposition by boiling with acids or alkalies.
It crystallises in white, or yellowish white needles, containing 1
mol. (9·5 per cent.) of water, which it loses at 212° F. (100° C.).
It is soluble in 100 parts of cold or 3 of boiling water, in alcohol
or glycerin, and slightly so in ether, by agitation with which it may
however be removed from its aqueous solution. Gallic acid fuses at a
temperature of about 449° F. (232° C.) (Etti, Chem. Soc. Jour., xxxvi.
160), but at about 410° F. (210° C.) begins to lose carbonic dioxide,
and yields a crystalline sublimate of pyrogallol (see p. 66). If the
heat be raised suddenly to 482° F. (250° C.) a considerable quantity of
black shining metagallic acid is formed.
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