Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
The argument is sometimes advanced that an acetylene generator containing
carbide in excess will work satisfactorily without exhibiting an
undesirable rise in internal temperature, if the vessel holding the
carbide is merely surrounded by a large quantity of cold water. The idea
is that the heat evolved in that particular portion of the charge which
is suffering decomposition will be communicated with sufficient speed
throughout the whole mass of calcium carbide present, whence it will pass
through the walls of the containing vessel into the water all round.
Provided the generator is quite small, provided the carbide container is
so constructed as to possess the maximum of superficial area with the
minimum of cubical capacity (a geometrical form to which the sphere, and
in one direction the cylinder, are diametrically opposed), and provided
the walls of the container do not become coated internally or externally
with a coating of lime or water scale so as to diminish in heat-
transmitting power, an apparatus designed in the manner indicated is
undoubtedly free from grave objection; but immediately any of those
provisions is neglected, trouble is likely to ensue, for the heat will
not disappear from the place of actual reaction at the necessary speed.
Apparent proof that heat is not accumulating unduly in a water-jacketed
carbide container even when the generator is evolving gas at a fair speed
is easy to obtain; for if, as usually happens, the end of the container
through which the carbide is inserted is exposed to the air, the hand may
be placed upon it, and it will be found to be only slightly warm to the
touch. Such a test, however, is inconclusive, and frequently misleading,
because if more than a pound or two of carbide is present as an undivided
mass, and if water is allowed to attack one portion of it, that
particular portion may attain a high temperature while the rest is
comparatively cool: and if the bulk of the carbide is comparatively cool,
naturally the walls of the containing vessel themselves remain
practically unheated. Three causes work together to prevent this heat
being dissipated through the walls of the carbide vessel with sufficient
rapidity. In the first place, calcium carbide itself is a very bad
conductor of heat. So deficient in heat-conducting power is it that a
lump a few inches in diameter may be raised to redness in a gas flame at
one spot, and kept hot for some minutes, while the rest of the mass
remains sufficiently cool to be held comfortably in the fingers. In the
second place, commercial carbide exists in masses of highly irregular
shape, so that when they are packed into any vessel they only touch at
their angles and edges; and accordingly, even if the material were a
fairly good heat conductor of itself, the air or gas present between each
lump would act as an insulator, protecting the second piece from the heat
generated in the first. In the third place, the calcium hydroxide
Public-domain text, read in full here on John Shaqi.
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