Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power — John Shaqi
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
produced as the by-product when calcium carbide is decomposed by water
occupies considerably more space than the original carbide--usually two
or three times as much space, the exact figures depending upon the
conditions in which it is formed--and therefore a carbide container
cannot advisedly be charged with more than one-third the quantity of
solid which it is apparently capable of holding. The remaining two-thirds
of the space is naturally full of air when the container is first put
into the generator, but the air is displaced by acetylene as soon as gas
production begins. Whether that space, however, is occupied by air, by
acetylene, or by a gradually growing loose mass of slaked lime, each
separate lump of hot carbide is isolated from its neighbours by a
material which is also a very bad heat conductor; and the heat has but
little opportunity of distributing itself evenly. Moreover, although iron
or steel is a notably better conductor of heat than any of the other
substances present in the carbide vessel, it is, as a metal, only a poor
conductor, being considerably inferior in this respect to copper. If heat
dissipation were the only point to be studied in the construction of an
acetylene apparatus, far better results might be obtained by the
employment of copper for the walls of the carbide container; and possibly
in that case a generator of considerable size, fitted with a water-
jacketed decomposing vessel, might be free from the trouble of
overheating. Nevertheless it will be seen in Chapter VI. that the use of
copper is not permissible for such purposes, its advantages as a good
conductor of heat being neutralised by its more important defects.
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