Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and PowerLeeds, F. H. (Frank Henley)
Science
Acetylene, the Principles of Its Generation and Use: A Practical Handbook on the Production, Purification, and Subsequent Treatment of Acetylene for the Development of Light, Heat, and Power
Leeds, F. H. (Frank Henley)
Acetylene
hour, maximum thermometers placed immediately over the carbide in the
different cells gave readings of from 70° to 90° C., the average maximum
temperature being about 80° C. Hence the Austrian code of rules issued in
1905 governing the construction of acetylene apparatus contains a clause
to the effect that the temperature in the gas space of a generator must
never exceed 80° C.; whereas the corresponding Italian code contains a
similar stipulation, but quotes the maximum temperature as 100° C.
(_vide_ Chapter IV.).
It is now necessary to see why the production of an excessively high
temperature in an acetylene generator has to be avoided. It must be
avoided, because whenever the temperature in the immediate neighbourhood
of a mass of calcium carbide which is evolving acetylene under the attack
of water rises materially above the boiling-point of water, one or more
of three several objectionable effects is produced--(_a_) upon the
gas generated, (_b_) upon the carbide decomposed, and (_c_)
upon the general chemical reaction taking place.
It has been stated above that in moat generators when the action between
the carbide and the water is proceeding smoothly, it occurs according to
equation (2)--
(2) CaC_2 + 2H_2O = C_2H_2 + Ca(OH)_2
rather than in accordance with equation (1)--
(1) CaC_2 + H_2O = C_2H_2 + CaO.
This is because calcium oxide, or quicklime, the by-product in (1), has
considerable affinity for water, evolving a noteworthy quantity of heat
when it combines with one molecule of water to form one molecule of
calcium hydroxide, or slaked lime, the by-product in (2). If, then, a
small amount of water is added to a large amount of calcium carbide, the
corresponding quantity of acetylene may be liberated on the lines of
equation (1), and there will remain behind a mixture of unaltered calcium
carbide, together with a certain amount of calcium oxide. Inasmuch as
both these substances possess an affinity for water (setting heat free
when they combine with it), when a further limited amount of water is
introduced into the mixture some of it will probably be attracted to the
oxide instead of to the carbide present. It is well known that at
ordinary temperatures quicklime absorbs moisture, or combines with water,
to produce slaked lime; but it is equally well known that in a furnace,
at about a red heat, slaked lime gives up water and changes into
quicklime. The reaction, in fact, between calcium oxide and water is
reversible, and whether those substances combine or dissociate is simply
a question of temperature. In other words, as the temperature rises, the
heat of hydration of calcium oxide diminishes, and calcium hydroxide
becomes constantly a less stable material. If now it should happen that
the affinity between calcium carbide and water should not diminish, or
should diminish in a lower ratio than the affinity between calcium oxide
and water as the temperature of the mass rises from one cause or other,
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