Acids, Alkalis and SaltsAdlam, George Henry Joseph
Science
Acids, Alkalis and Salts
Adlam, George Henry Joseph
Acids; Alkalies; Salts
The current enters the end compartments by the carbon anodes and passes
through the salt solution to the mercury layer which in these
compartments are the cathodes. The current then passes through the
mercury to the middle compartment, and then through the solution to the
cathode, thence back to the dynamo. It is important to note that in the
middle compartment the mercury becomes the anode.
Chlorine is liberated at the carbon electrodes, and when no more can
dissolve in the liquid it escapes and is conveyed away by the pipe P.
Sodium atoms are formed at the surface of the mercury cathodes in the
outside compartments and dissolve instantly in the mercury, forming
sodium amalgam.
While the current is passing, a slight rocking motion is given to the
tank by the cam E. This is sufficient to cause the mercury containing
the dissolved sodium to flow alternately into the middle compartment,
and there the sodium amalgam comes into contact with water; the sodium
is dissolved out of the mercury and caustic soda is formed. Water in a
regulated stream is constantly admitted to the middle compartment, and a
solution of caustic soda of about 20 per cent. strength overflows.
The production of caustic soda by an electrical method still remains to
be fully developed. A process which gives only a 20 per cent. solution
cannot be looked upon as final. In the meantime, other methods have been
tried, in some of which fused salt is used in place of brine in order to
give caustic soda in a more concentrated form. For a description of
these methods, the reader must consult some of the larger works
mentioned in the preface. Here we can only say that very great
difficulties have been encountered, particularly in the construction of
a satisfactory porous diaphragm or, alternately, in devising methods in
which this can be dispensed with.
Another interesting application of electrolysis is furnished by the use
of copper sulphate in industry. When this salt is dissolved in water, it
breaks up into copper ions (positive) and an equal number of negative
ions, composed of 1 atom of sulphur and 4 atoms of oxygen (SO″4). Under
the influence of the current copper ions travel to the cathode, and
there by the gain of two electrons become copper atoms. Now, since
copper is not soluble in copper sulphate solution, and is not volatile
except at very high temperatures, it is deposited on the cathode in a
perfectly even and continuous film when the strength of the current is
suitably adjusted. This film continues to grow in thickness as long as
the conditions for its deposition are maintained. If the current
employed is not suitable, the metallic film is not coherent, and the
copper may appear as a red powder at the bottom of the cell. Any other
metal or impurity which might be present in the unrefined copper falls
to the bottom of the tank.
Public-domain text, read in full here on John Shaqi.
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