The attraction of moisture by gunpowder, is known to be very great:
according to Rees's Cyclopedia, upwards of 16 per cent. has been
absorbed, and that the removal, simply, from near the fire to the
corner of the room, produces a considerable change in its weight.
I presume, therefore, that the lime, which in its caustic state
has also a great affinity to water, attracts a portion of it from
the powder, and leaves it in a state of dryness best fitted for
inflammation. But if the lime should remain too long mixed with
the powder, it would probably attack the water of crystallization
of the saltpetre, and, according to Count Rumford's idea, destroy
a great part of the power. If also left exposed, attractions of
moisture would take place from the atmosphere, the gunpowder would
remain surcharged with humidity as before, and the lime would be
only an inert mass.
The examination of this subject led me to consider the increase
of the power of gunpowder in various situations, and of its use
in the field. It is well known that after a few discharges a
cannon becomes heated, and the range is much greater, as well as
the recoil. The charge of powder is therefore reduced about one
quarter, to produce the original effect. As I have not heard or
seen any explanation of this fact I shall take this opportunity of
mentioning, that it appears to arise from the same cause as the
first explained, viz. the desiccation of the powder. No person will
dispute the heat acquired by a cannon, or even a musket, after
repeated discharges; and this heat must volatilize or destroy a
great portion of the moisture combined with the powder, assist its
speedy inflammation, and perhaps add to its power, by causing a
more perfect combustion of the inflammable parts of the gunpowder.
This would cause a much greater volume of gas to be produced, and
the high temperature would also greatly augment its elasticity;
and it is well known that the effects of gunpowder depend upon the
rapid production and high degree of elasticity of a great quantity
of aeriform fluids or gases.
ART. XX. _On The Connexion between Magnetism and Light._ By Col.
GIBBS.
_Extract from a Letter to the Editor._
Public-domain text, read in full here on John Shaqi.
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