An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Chemical properties.~ Nitrogen is characterized by its inertness. It is
neither combustible nor a supporter of combustion. At ordinary
temperatures it will not combine directly with any of the elements
except under rare conditions. At higher temperatures it combines with
magnesium, lithium, titanium, and a number of other elements. The
compounds formed are called _nitrides_, just as compounds of an element
with oxygen are called _oxides_. When it is mixed with oxygen and
subjected to the action of electric sparks, the two gases slowly combine
forming oxides of nitrogen. A mixture of nitrogen and hydrogen when
treated similarly forms ammonia, a gaseous compound of nitrogen and
hydrogen. Since we are constantly inhaling nitrogen, it is evident that
it is not poisonous. Nevertheless life would be impossible in an
atmosphere of pure nitrogen on account of the exclusion of the necessary
oxygen.
~Argon, helium, neon, krypton, xenon.~ These are all rare
elements occurring in the air in very small quantities. Argon,
discovered in 1894, was the first one obtained. Lord Rayleigh,
an English scientist, while engaged in determining the exact
weights of various gases, observed that the nitrogen obtained
from the air is slightly heavier than pure nitrogen obtained
from its compounds. After repeating his experiments many times,
always with the same results, Rayleigh finally concluded that
the nitrogen which he had obtained from the air was not pure,
but was mixed with a small amount of some unknown gas, the
density of which is greater than that of nitrogen. Acting on
this assumption, Rayleigh, together with the English chemist
Ramsay, attempted to separate the nitrogen from the unknown
gas. Knowing that nitrogen would combine with magnesium, they
passed the nitrogen obtained from the air and freed from all
known substances through tubes containing magnesium heated to
the necessary temperature. After repeating this operation, they
finally succeeded in obtaining from the atmospheric nitrogen a
small volume of gas which would not combine with magnesium and
hence could not be nitrogen. This proved to be a new element,
to which they gave the name _argon_. As predicted, this new
element was found to be heavier than nitrogen, its density as
compared with hydrogen as a standard being approximately 20,
that of nitrogen being only 14. About 1% of the atmospheric
nitrogen proved to be argon. The new element is characterized
by having no affinity for other elements. Even under the most
favorable conditions it has not been made to combine with any
other element. On this account it was given the name argon,
signifying lazy or idle. Like nitrogen, it is colorless,
odorless, and tasteless. It has been liquefied and solidified.
Its boiling point is -187 deg..
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