An Elementary Study of ChemistryMcPherson, William
Science
An Elementary Study of Chemistry
McPherson, William
Chemistry
~Why the air has a constant composition.~ If air is a mixture and changes
are constantly taking place which tend to modify its composition, how,
then, do we account for the constancy of composition which the analyses
reveal? This is explained by several facts. (1) The changes which are
caused by the processes of combustion and respiration, on the one hand,
and the action of plants, on the other, tend to equalize each other. (2)
The winds keep the air in constant motion and so prevent local changes.
(3) The volume of the air is so vast and the changes which occur are so
small compared with the total amount of air that they cannot be readily
detected. (4) Finally it must be noted that only air collected in the
open fields shows this constancy in composition. The air in a poorly
ventilated room occupied by a number of people rapidly changes in
composition.
~The properties of the air.~ Inasmuch as air is composed principally of a
mixture of oxygen and nitrogen, which elements have already been
discussed, its properties may be inferred largely from those of the two
gases. One liter weighs 1.2923 g. It is thus 14.38 times as heavy as
hydrogen. At the sea level it exerts an average pressure sufficient to
sustain a column of mercury 760 mm. in height. This is taken as the
standard pressure in determining the volumes of gases as well as the
boiling points of liquids. Water may be made to boil at any temperature
between 0 deg. and considerably above 100 deg. by simply varying the pressure.
It is only when the pressure upon it is equal to the normal pressure of
the atmosphere at the sea level, as indicated by a barometric reading of
760 mm., that it boils at 100 deg..
~Preparation of liquid air.~ Attention has been called to the fact that
both oxygen and nitrogen can be obtained in the liquid state by strongly
cooling the gases and applying great pressure to them. Since air is
largely a mixture of these two gases, it can be liquefied by the same
methods.
The methods for liquefying air have been simplified greatly in
that the low temperature required is obtained by allowing a
portion of the compressed air to expand. The expansion of a gas
is always attended by the absorption of heat. In liquefying air
the apparatus is so constructed that the heat absorbed is
withdrawn from air already under great pressure. This process
is continued until the temperature is lowered to the point of
liquefaction.
[Illustration: Fig. 29]
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