An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
Examine brass, bronze, bell-metal, pewter, German silver, solder,
type-metal.
223. Alloys.-An alloy is not usually a definite chemical
compound, but rather a mixture of two or more metals which are
melted together. One metal may be said to dissolve in the other,
as sugar dissolves in water. The alloy has, however, different
properties from those of its elements. For example, plumber's
solder melts at a lower temperature than either Ph or Sn, of
which it is composed. Some metals can alloy in any proportions.
Solder may have two parts of Sn to one of Pb, two of Pb to one of
Sn, or equal parts of each, or the two elements may alloy in
other proportions. Not all metals can be thus fused together
indefinitely; e.g., Zn and Pb. Nickel and silver coins are
alloyed with Cu, gold coins with Cu and Ag.
Gun-metal, bell-metal, and speculum-metal are each alloys of Cu
and Sn. Speculum-metal, used for reflectors in telescopes, has
relatively more Sn than either of the others; gun-metal has the
least. An alloy of Sb and Pb is employed for type-metal as it
expands at the instant of solidification. Pewter is composed of
Sn and Pb; brass, of Cu and Zn; German silver, of brass and Ni;
bronze, of Cu, Sn, and Zn; aluminium bronze, of Cu and Al.
224. Low Fusibility is a feature of many alloys. Wood's metal,
composed of Pb eight parts, Bi fifteen, Sn four, Cd three, melts
at just above 60 degrees, or far below the boiling-point of
water. By varying the proportions, different fusing-points are
obtained. This principle is applied in automatic fire alarms, and
in safety plugs for boilers and fire extinguishers. Water pipes
extend along the ceiling of a building and are fitted with plugs
of some fusible alloy, at short distances apart. When, in case of
fire, the heat becomes sufficiently intense, these plugs melt and
the water flows out.
225. Amalgams.--An amalgam is an alloy of Hg and another metal.
Mirrors are "silvered" with an amalgam of Sn. Tin-foil is spread
on a smooth surface and covered with Hg, and the glass is pressed
thereon.
Various amalgams are employed for filling teeth, a common one
being composed of Hg, Ag, and Sn. Au or Ag, with Hg, forms an
amalgam used for plating. Articles of gold and silver should
never be brought in contact with Hg. If a thin amalgam cover the
surface of a gold ring or coin, Hg can be removed with HNO3, as
Au is not attacked by it. Would this acid do in case of silver
amalgam? Heat will also quickly cause Hg to evaporate from Au.
CHAPTER XLIV.
SODIUM AND ITS COMPOUNDS.
Examine NaCl, Na2SO4, Na2CO3, Na, NaOH, HNaCO3, NaNO3.
226. Order of Derivation.--Though K is more metallic, or electro-
positive, than Na, the compounds of Na are more important, and
will be considered first. The only two compounds of Na which
occur extensively in nature are NaCl and NaNO3. Almost all others
are obtained from NaCl, as shown by this table, which should be
memorized and frequently recalled.
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