An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
249. Occurrence.--The above are the chief compounds of Ca. The
element itself is not found uncombined, is very difficult to
reduce (page 141), is a yellow metal, and has no use. Its most
abundant compound is CaCO3. Shells of oysters, clams, snails,
etc., are mainly CaCO3, and coral reefs, sometimes extending
thousands of miles in the ocean, are the same. CaCO3 dissolves in
water holding CO2, and thence these marine animals obtain it and
therefrom secrete their bony framework. All mountains were first
laid down on the sea bottom layer by layer, and afterwards lifted
up by pressure. Rocks and mountains of CaCO3 were formed by
marine animals, and all large masses of CaCO3 are thought to have
been at one time the framework of animals. Marble is
crystallized, transformed limestone. The process, called
metamorphism, took place in the depths of the earth, where the
heat is greater than at the surface.
250. Lime.--If CaCO3 be roasted with C, CO2 escapes and CaO is
left. CaCO3 - CO2 = ? This is called burning lime, and is a large
industry in limestone countries. CaO is unslaked lime, quicklime
or calcium oxide. It may be slaked either by exposure to the
air, air-slaking, when it gradually takes up H2O and CO2; or by
mixing with H2O, water-slaking. Ca0 + H2O = Ca(OH)2.
Great heat is generated in the latter case, though not so much as
in the formation of KOH and NaOH. Like them, Ca(OH)2 dissolves in
water, forming lime-water. Milk of lime, cream of lime, etc.,
consist of particles of Ca(OH)2 suspended in H2O.
251. Uses of Lime--CaO is infusible at the highest temperatures.
If it be introduced into the oxy-hydrogen blow-pipe (page 28), a
brilliant light, second only to the electric, is produced. Mortar
is made by mixing CaO, H2O, and Si02. It hardens by evaporating
the extra H2O, absorbing CO2 from the air, and uniting with Si02
to form calcium silicate. It often continues to absorb CO2 for
hundreds or thousands of years before being saturated, as is
found in the Egyptian pyramids. Hence the tenacity of old mortar.
Hydraulic mortar contains silicates of Al and Ca, and is not
affected by water. What are the uses of mortar? Being the
important constituent of mortar and plaster, lime is the most
useful of the bases.
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