An Introduction to Chemical ScienceWilliams, Rufus P. (Rufus Phillips)
Science
An Introduction to Chemical Science
Williams, Rufus P. (Rufus Phillips)
Chemistry
What is the chief use of Na? As it takes three pounds of Na to
make one pound of Al, the cost of the latter has been fifteen
dollars or more per pound. Its use has thus been restricted to
light apparatus and aluminium bronze, an alloy of Cu 90, Al 10,
which is not unlike gold in appearance.
Al2O3 has lately been reduced by C. Higher temperatures than have
heretofore been known are obtained by means of the electric arc
and large dynamo machines. Afurnace made of graphite, because
fire-clay melts like wax at such a high temperature, is filled
with Al2O3--corundum, --C, and Cu. In the midst of this are
embedded large carbon terminals, connected with dynamos. The
reduction takes several hours.
The following reaction takes place: Al2O3 + 3 C = 2 Al + 3 CO. Cu
is also added, and an alloy of Al and Cu is thus formed. This
alloy is not easily separable into its elements. Explain the
action of the C. CO escapes through perforations in the top of
the furnace, burning there to CO2. Only alloys of Al have yet
been obtained by this process. This method has not been employed
before, simply because the highest temperatures of combustion,
2000 degrees or 2500 degrees, would not effect a reduction. In
the same way Si, B, K, Na, Ca, Mg, Cr, have recently been reduced
from their oxides; but a process has yet to be found for
separating them easily from their alloys.
262. Properties and Uses.--Al is a silvery white metal, lighter
than glass, and only one-third the weight of iron. It does not
readily rust or oxidize, it fuses at 1000 degrees (compare with
Fe), is unaffected by acids, except by HCl and, slightly, by
H2SO4, is a good conductor of electricity, can be cast and
hammered, and alloys with most metals, forming thus many valuable
compounds. Every clay-bank is a mine of this metal, which has so
many of the useful properties of metals and has so few defects
that, if it could be obtained in sufficient quantities, it might,
for many purposes, take the place of iron, steel, tin, and other
metals. From its properties state any advantages which it would
have over iron in ocean vessels, railroads, and bridges. Why is
it better than Sn or Cu for culinary utensils? An alloy of Al,
Cu, and Si is used for telephone wires in Europe, and the
Bennett-Mackay cable is of the same material. Washington
monument, the tallest shaft in the world, is capped with a
pyramid of Al,ten inches high.
For the uses of alumina, Al2O3, and its silicates, see page 133.
ZINC AND ITS COMPOUNDS.
Examine zincite, sphalerite, Smithsonite, sheet zinc, galvanized
iron, granulated zinc, zinc dust.
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