Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899Various
Religion
Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899
Various
Science -- Periodicals; Technology -- Periodicals
In May, 1892, Mr. Thomas Willson, a Canadian electrician, tried to
make the metal calcium in an electric furnace in his works at Spray,
North Carolina, by heating a mixture of lime and coal dust. He thought
that the lime (calcium oxide) would act on the coal (carbon) to form
calcium and carbon monoxide. He did not succeed in getting calcium,
but found in the furnace a brown, crystalline mass, which was
decomposed by pouring water on it, yielding an inflammable gas.
Willson is not a chemist, and he therefore sent specimens of the
material to several men of science to determine its nature. It was
shown to be calcium carbide, a compound of calcium and carbon, formed
by the action of the carbon on the calcium oxide. The reaction
expressed in chemical symbols is CaO + 3C = CaC_{2} + CO. The gas
formed by the action of water was acetylene, a compound of carbon and
hydrogen. The reaction is CaC_{2} + H_{2}O = C_{2}H_{2} + CaO; calcium
carbide and water form acetylene and lime. If water enough is added,
the lime is slaked, and slaked lime, or calcium hydroxide, Ca(OH_{2}),
is formed. Neither calcium carbide nor acetylene was a new discovery;
acetylene was discovered by Edmund Davy in 1836, and its properties
were studied by Berthelot in 1862. Impure calcium carbide was first
made in 1862 by Wöhler, who described its decomposition by water into
acetylene and lime. What was there new, then, in Willson's discovery?
Two important facts: (1) He was the first to make carbide by a method
applicable commercially; (2) he was the first to make crystalline
carbide. Wöhler's carbide was impure and amorphous; Willson's, nearly
pure and crystalline, so that he succeeded in obtaining United States
patents for crystalline carbide, and, as all carbide made by
commercial processes is crystalline, its manufacture is covered by
Willson's patents.
In the same year, 1892, Prof. Henri Moissan, of Paris, announced the
discovery of crystalline calcium carbide. Moissan's discovery, too,
was an accidental one. He was reducing refractory metallic oxides in
an electric furnace made of lime. At the close of the article in which
he reports his work to the French Academy of Sciences (_Comptes Rendus
de l'Académie Française_, vol. cxii, page 6, December 12, 1892) he
refers in two lines to the formation of an ill-defined carbide of
calcium by the action of the carbon electrodes on the lime of which
his furnace was made.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account