Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899Various
Religion
Appletons' Popular Science Monthly, July 1899: Volume LV, No. 3, July 1899
Various
Science -- Periodicals; Technology -- Periodicals
large volume of acetylene escaped and ignited from a lighted candle.
In all four cases the explosions were caused by ignorance or
carelessness incident to the beginnings of a new industry, and could
be avoided by experience and skill.
It should be stated that in the explosion at Paris all of the full
acetylene cylinders were dug out of the ruins unhurt. The same was
true at Berlin, where five full cylinders were blown against the wall
of the building by the explosion of the condenser, but did not
explode. At Jersey City sixty filled cylinders were exposed to the
heat of the fire following the explosion; they were fitted with safety
diaphragms of fusible metal; forty-eight remained intact, the
acetylene burning off quietly as it escaped through the fused
diaphragm, and twelve exploded, either on account of imperfection of
the diaphragms or stoppage of the air passage leading from the
diaphragm. The explosions of liquid acetylene in buildings of
consumers have been due in every case to gross carelessness and
ignorance on the part of the consumer.
Although one of the chief points in favor of the liquid acetylene is
its portability, yet it can be shown that it is still easier to carry
carbide to the consumer. One cubic metre of acetylene is compressed to
two litres in liquid form; two litres of carbide weigh 4.44
kilogrammes, which will produce a cubic metre and a third of
acetylene, reckoning three hundred litres to the kilogramme, which is
the average guaranteed yield of carbide. The light tin carbide cans
occupy less space and weigh less than the heavy steel cylinders, while
the generation of the gas is simple and, with proper generators,
perfectly safe. On the other hand, the generators must be cared for,
must often be filled with fresh carbide, and from time to time must be
cleaned. With the generator system acetylene is as safe as or safer
than illuminating gas. Berthelot has shown that at pressures below two
atmospheres a vessel filled with acetylene can not be exploded by the
explosion of a cap of fulminating mercury within the vessel, nor by
heating a wire which extends into the vessel to a white heat by an
electric current. The reason is that the acetylene can not explode
unless it is decomposed into its elements, carbon and hydrogen; to
decompose it requires a certain amount of energy. While the energy of
the glowing wire or of the exploding cap causes a local decomposition
at the point of contact, it is not sufficient to spread the
decomposition further. Acetylene forms an explosive mixture with air;
so does illuminating gas. The odor of acetylene is unpleasant; so is
the odor of the water gas used generally in the United States, and the
acetylene can be cheaply deodorized.
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