British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
effervescence will take place, owing to the expulsion of carbonic acid
from the carbonate of soda and potash by means of the silicic acid. If
the operation be performed in such a vessel that the carbonic acid can
be collected, its presence is readily indicated by the usual tests.
This experiment can be easily made by anyone who has ordinary chemical
apparatus at his command. If the mixture of carbonate of potash and
carbonate of soda be melted in a small platinum crucible; and if, when
melted, it be removed quickly while very hot into a tall beaker-glass,
and sand be then poured into it, the escaping carbonic acid will, on
account of its being heavier than air, be retained in the glass, and
its presence can be recognized by its turning lime-water milky (which
is, in fact, a solution of lime in water), owing to the formation of
carbonate of lime produced by the carbonic acid evolved uniting with
the lime dissolved in the water. A mixture of carbonate of soda and
carbonate of potash is here used, because either of these salts
requires a very high temperature to melt it; but when the two are
heated together, the fusibility of both is increased. When sand is
heated with oxide of lead (common litharge) they unite, forming a
compound similar to that produced by the silica uniting with the soda,
as described in the last paragraph. In the first case, a _soda_ glass
is formed; in the second, a _lead_ glass is the result. If these two
glasses be mixed together and melted in a crucible, and if the
proportions in which they are mixed be properly adjusted, and the
materials used be pure, a colourless and transparent glass will be
formed, similar in appearance to that which is employed in the
manufacture of decanters and tumblers. The same kind of glass may be
produced by mixing all the materials in due proportions and heating
them together. If, instead of oxide of lead, lime be mixed with
carbonate of soda and sand, and the mixture be heated to a high
temperature, a glass will be formed, in many respects similar to that
of which oxide of lead is a constituent, but differing from it in
several important particulars. First of all, the lead glass is highly
lustrous, and has a great power of refracting light, so that, when it
is cut, it presents a brilliant appearance, and by refraction readily
produces the prismatic colours. This property does not belong to the
glass containing lime, to anything like the same extent. Lead glass,
too, is much heavier than lime glass, and is therefore unsuited to
many of the purposes for which the latter is generally used, the
principal of which is for the glazing of windows.
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