British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
If, instead of oxide of lead, which is a chemical compound of lead and
oxygen gas, or lime, which likewise is one of the metal calcium with
oxygen, _carbonate_ of lead or of lime be used, the silicic acid will
expel the carbonic acid from these substances at a high temperature,
just as it does the carbonic acid from the carbonate of soda and
carbonate of potash. It is necessary, for a proper understanding of
the scientific part of our subject, that this fact should be borne in
mind, and that the acid properties of silica should be thoroughly
recognized. Formerly, carbonate of soda was used in the manufacture of
ordinary window glass, but now it is found more economical to employ
_sulphate_ of soda, which is a much earlier product in the manufacture
of soda from common salt than the carbonate, and is therefore less
expensive. Carbonic acid is what chemists call a _weak_ acid, by which
is meant, that its compounds are not so firm and stable, as those
which are formed by other acids with the same substances. Sulphuric
acid is a strong and powerful acid, uniting very readily with the
oxides of certain metals to form very stable compounds. But although
this acid is chemically so powerful in its compounds, yet at a high
temperature it is expelled by silicic acid, showing that this
substance, so inert in its natural state and at the ordinary
temperature of the air, becomes exceedingly active in expelling other
acids and in forming compounds, when put under favourable conditions.
If a mixture of common sand and carbonate of soda, the carbonate of
soda being in excess, be heated, a glass will be obtained which is
slowly soluble in cold, readily soluble in hot water. To these
compounds the name of silicate is given, so that we speak of the soda
compound as silicate of soda, of the lead compound as silicate of
lead, and the lime compound as silicate of lime. Silicate of soda and
silicate of potash, when the alkali, that is to say, the soda or
potash, is in excess, are both soluble. If a solution of one of these
silicates be taken, and if carbonic acid be passed slowly through it,
after a time a gelatinous, white, flocculent substance will be formed
in the liquid, and eventually precipitated. This white flocculent
substance is silicic acid combined with the elements of water, and is
therefore called by chemists hydrate of silica. Now this hydrate of
silica is soluble in water and in hydrochloric acid; and the method by
which it can be brought into solution in water will be explained, when
treating fully of what are called soluble silicates and their
applications.
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