British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
It has been noticed that the glass found in the windows of old
churches and in other places where it has been exposed to the
prolonged action of the air and of moisture, has gradually become
rough on its surface, and has lost to a considerable extent its
transparency. This, which would be a defect in glass for the glazing
of ordinary windows, where transparency is desired, is rightly
regarded as a beauty in glass which is to be used for the
ornamentation of windows. Many reasons have been offered in
explanation of this apparently peculiar property of ancient glass; and
that which appears to be correct is, that glass is a mechanical
mixture of different silicates, some of which may be soluble in water,
and others insoluble. The old window glass, whose manufacture will be
more fully described by-and-by, was made in a less perfect manner than
modern appliances enable glass manufacturers now to produce the same
article, so that the silicates composing the old glass were not as
intimately mixed as those used in modern glass. By the slow action of
air and moisture, portions of the soluble silicates have been
dissolved out, and hence we frequently find a sort of honeycomb
appearance on the surface of ancient glass, as well as a thin film,
which, by refraction of light, causes an opalescence when viewed by
reflected light. Efforts have of late been made to produce a similar
effect by employing different methods in the process of manufacture,
but without complete success. The fact, however, that such changes
have taken place in this less perfectly fused glass, tends to show,
that if one silicate can be dissolved out, there cannot be _chemical_
union between all the silicates. If a piece of modern window glass be
heated in water under pressure in a closed vessel, it will present
somewhat the appearance of ancient glass, for a considerable quantity
of soluble silicate will be dissolved out from it. The object in
dwelling on this matter here, is to induce makers to attend more to
the chemical composition of their glass, for, doubtless, much more
satisfactory results would be obtained both as to the quality of the
material and the cost of its production, if thoroughly scientific
investigations were conducted by a competent chemist.
MANUFACTURE OF GLASS.
The first object in glass making is to obtain suitable materials. The
sand which is employed for window glass differs from that which is
required for flint glass, in that the latter should be as pure as
possible. The maker can correct the impurities in the window glass
sand, provided they be not present in too great quantities; but it is
far more difficult, in the case of flint glass, to chemically
counteract the influence of those substances which might impair its
tint. So that the manufacturer would rather pay large prices for his
sand, than trust to expedients which in their application might fail,
and thus cause a greater loss.
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