British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.Arnoux, Léon
History
British Manufacturing Industries: Pottery, Glass and Silicates, Furniture and Woodwork.
Arnoux, Léon
Manufacturing industries -- Great Britain
Having considered briefly the manufacture of glass-pots, I shall
proceed to the treatment of the materials to be employed. In making
common window glass, ordinary sand, which does not contain any very
large quantity of iron, may be used, the alkali employed being
sulphate of soda, while the purifying material is either arsenic or
black oxide of manganese. A small quantity of anthracite coal is added
to the mixture, in order to assist in the reduction of the sulphate of
soda, together with some lime. The materials are carefully mixed and
placed in the furnace, where they are heated for some time, a process
which is called "fritting." Its object is to perfectly dry the
materials, so as to expel carbonic acid gas, which would otherwise
cause swelling in the glass; but no combination must take place, to
allow of silicates being formed, otherwise the alkali would melt first
and attack the substance of the glass-pots, and part of it would be
volatilized and lost. When this operation is completed, the fritt is
put into the hot glass-pot, and submitted to the action of the heat of
the furnace, until the glass is made, or "founded," as it is
technically termed. In the case of sheet and crown glass, this process
lasts from sixteen to seventeen hours, for it will be remembered that
the top of the pot is open to the furnace, so that the flames pass
over the surface of its contents. In this way the materials get heated
more rapidly than when a covered glass-pot is used.
M. Gehlen gives as a good mixture for window glass:
Sand 100 parts.
Dry sulphate of soda 50 "
Quicklime 20 "
Carbon, as charcoal 4 "
Different makers have different mixtures. This by M. Gehlen is given
as _about_ the proportions of the several constituents employed.
The charging of the pots is conducted in this manner: they are filled
with lumps of fritt, and the heat of the furnace is raised as rapidly
as possible, until, in about eight or nine hours the fritt has run
down or melted into glass. More fritt is then added, which also melts,
and from time to time this is repeated, till the pot contains a
sufficient quantity. After about sixteen hours the whole has become
converted into glass, and the surface of the molten mass is covered
with liquid salt and sulphate of soda. This scum is called glass-gall
or sandiver, and is carefully removed with iron ladles. Some broken
glass, or cullet, is now thrown into the glass-pot, a little at a
time, the object being to cause any salt which may remain in the pot
to rise to the surface, which is then removed, and so the glass is in
this manner purified, after it has been further heated for some hours,
to expel gases.
Public-domain text, read in full here on John Shaqi.
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