Bleach is being very extensively used for the sterilisation of the water
used by the allied troops in France. The water supplies on the British
front are all more or less subject to pollution and it is consequently
necessary, to ensure adequate protection, to chlorinate all supplies
with bleach. Other forms of chlorine have been tried but have not proved
successful near the firing lines. The details of the technique employed
cannot be given but it may be stated that the concentration of chlorine
employed is always more than sufficient and that residual tastes and
odours are regarded as secondary considerations. Treated water is always
tested by the starch-iodide method and a bacteriological examination is
frequently made by mobile laboratories.
=Control of Hypochlorite Plants.= If efficient operation and regular
dosage is to be obtained, it is necessary that hypochlorite plants
should be controlled by a trained chemist. Good results are occasionally
obtained without such control but in every plant circumstances arise at
some period or another which only a chemist is qualified to deal with.
The points that require consideration are (1) the composition of the
bleach; (2) concentration of available chlorine in the prepared
solutions; and (3) chemical tests for free chlorine in the treated
water.
(1) _Composition of Bleach._ Each drum of bleach should be sampled and
analysed before use. The sample is obtained by cutting out the head of
the drum and removing a vertical section by means of a special sampling
tube or a piece of half-inch iron pipe which is forced to the bottom of
the drum with a boring motion and then removed; the core is then forced
out by means of a rod, mixed, and quartered down to the required size.
For analysis weigh out 5 grms. on a balance sensitive to 0.01 grm. and
grind in a mortar with 50-70 c.cms. of water; wash into a 250 c.cm.
flask and make the volume up to 250 c.cms.; shake. After allowing the
sludge to settle remove 10 c.cms. by means of a pipette and titrate by
one of the following methods:
_Bunsen's Method._ Add 10 c.cms. of a 5 per cent solution of potassium
iodide and 0.5 c.cm. glacial acetic acid and titrate with sodium
thiosulphate (24.8 grms. of the C.P. crystalline salt and 1 c.cm. of
chloroform per litre) using a starch solution as indicator. Each cubic
centimetre of thiosulphate used = 1.755 per cent of available chlorine
(1 c.cm. N/10 sodium thiosulphate = 0.00355 grm. available chlorine).
Public-domain text, read in full here on John Shaqi.
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