It has been explained that by the methylation of rosaniline Hofmann
obtained violet colouring-matters. Now as rosaniline is obtained by the
oxidation of a mixture of aniline and toluidine, it seems but natural that
if these bases were methylated first and then oxidized a violet dye would
be produced. The French chemist Lauth first obtained a violet
colouring-matter by this method in 1861. In 1866 this violet dye was
manufactured in France by Poirrier, and it is still made in large
quantities, being known under the name of "methyl violet." This
colouring-matter, and a bluer derivative of it discovered in 1868,
gradually displaced the Hofmann violets, chiefly owing to their greater
cheapness of production. We are thus introduced to methylated aniline as a
source of colouring-matters, and as the compound in question has many
different uses in the coal-tar industry, a few words must be devoted to
its technology.
Aniline, toluidine, and similar bases can be methylated by the action of
methyl iodide, but the cost of iodine is too great to enable this process
to be used by the manufacturer. Methyl chloride, however, answers equally
well, and this compound, which is a liquid of very low boiling point (-23 deg.
C.), is prepared on a large scale from the waste material of another
industry, viz. the beet-sugar manufacture. It is interesting to see how
distinct industries by chemical skill are made to act and react upon one
another. Thus the cultivation of the beet, as already explained, is
largely dependent on the supply of ammonia from gas-liquor. During the
refining of the beet-sugar, a large quantity of uncrystallisable treacle
is separated, and this is fermented for the manufacture of alcohol. When
the latter is distilled off there remains a spent liquor containing among
other things potassium salts and nitrogenous compounds. This waste liquor,
called "vinasse," is evaporated down and ignited in order to recover the
potash, and during the ignition, ammonia, tar, gas, and other volatile
products are given off. Among the volatile products is a base called
trimethylamine, which is a derivative of ammonia; the salt formed by
combining trimethylamine with hydrochloric acid when heated gives off
methyl chloride as a gas which can be condensed by pressure.
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